Direct microwave leaching conditions of rare earth elements in fluorescent wastes

A. Bilen*, B. Birol, M. N. Saridede, S. Kaplan, M. Sönmez

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The luminescent phosphor powder in the fluorescent lamp constitutes 2% of the lamp's weight. It can be mentioned that fluorescent wastes are a crucial raw material to produce rare earth oxides. In the present study, microwave leaching process was conducted to dissolve rare earth elements yttrium (Y), europium (Eu), and remaining rare earth elements (REEs) present in the phosphor powder of the fluorescent lamp, and the yields were compared. In the microwave leaching process, the effects of the temperature (80–160°C), acid type (hydrochloric acid (HCl), nitric acid (HNO3), sulphuric acid (H2SO4)), acid concentration (0.5–6 mol/L), solid to liquid ratio (0.1:10–0.5:10) and reaction time (5–90 min) parameters on leaching efficiencies of varying rare earth elements and calcium were investigated. The highest yield was obtained in the direct microwave leaching of fluorescent waste with the experimental conditions of 6 mol/L HCl, 160 °C, 0.1:10 solid-to-liquid ratio (S:L), and 90 min. Activation energy calculations were made, and kinetic models of the reactions were obtained, and it is observed that Y and Eu dissolution is diffusion-controlled, on the other hand, lanthanum (La), cerium (Ce), and terbium (Tb) were examined to be chemical reaction controlled. Moreover, calcium (Ca) and gadolinium (Gd) seem coherent with the mixed model. Concurrently, mathematical models of all experimental studies are created with the response surface Box-Behnken method and the correlation coefficients of all the models are over 90%.

Original languageEnglish
Pages (from-to)1165-1174
Number of pages10
JournalJournal of Rare Earths
Volume42
Issue number6
DOIs
Publication statusPublished - Jun 2024

Bibliographical note

Publisher Copyright:
© 2023 Chinese Society of Rare Earths

Keywords

  • Direct microwave leaching
  • Fluorescent waste
  • Kinetic models
  • Rare earth elements (REEs)
  • Response surface method

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