Determination of the monomer reactivity ratios for copolymerization of itaconic acid and acrylamide by conductometric titration method

C. Erbil; S. Özdemir; N. Uyanik

doi:10.1016/S0032-3861(99)00291-8

Determination of the monomer reactivity ratios for copolymerization of itaconic acid and acrylamide by conductometric titration method

C. Erbil^*, S. Özdemir, N. Uyanik

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Composition of low conversion itaconic acid-acrylamide (IA-AAm) copolymers synthesized with solution polymerization in aqueous medium by using potassium persulfate under nitrogen atmosphere were determined by conductometric titration method. The results were evaluated by various linear and nonlinear methods. The monomer reactivity ratios were found to be r_IA = 1.47 ± 0.03, r_AAm = 0.76 ± 0.02 with Fineman-Ross, r_IA = 1.25 ± 0.10, r_AAm = 0.67 ± 0.05 with Kelen-Tudos, r_IA = 1.65 ± 0.21, r_AAm = 0.88 ± 0.08 with Tidwell-Mortimer methods. For this system, the analysis of results show that IA is a more reactive monomer in IA-AAm copolymerization.

Original language	English
Pages (from-to)	1391-1394
Number of pages	4
Journal	Polymer
Volume	41
Issue number	4
DOIs	https://doi.org/10.1016/S0032-3861(99)00291-8
Publication status	Published - Feb 2000

Keywords

Acrylamide
Itaconic acid
Reactivity ratio

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10.1016/S0032-3861(99)00291-8

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title = "Determination of the monomer reactivity ratios for copolymerization of itaconic acid and acrylamide by conductometric titration method",

abstract = "Composition of low conversion itaconic acid-acrylamide (IA-AAm) copolymers synthesized with solution polymerization in aqueous medium by using potassium persulfate under nitrogen atmosphere were determined by conductometric titration method. The results were evaluated by various linear and nonlinear methods. The monomer reactivity ratios were found to be rIA = 1.47 ± 0.03, rAAm = 0.76 ± 0.02 with Fineman-Ross, rIA = 1.25 ± 0.10, rAAm = 0.67 ± 0.05 with Kelen-Tudos, rIA = 1.65 ± 0.21, rAAm = 0.88 ± 0.08 with Tidwell-Mortimer methods. For this system, the analysis of results show that IA is a more reactive monomer in IA-AAm copolymerization.",

keywords = "Acrylamide, Itaconic acid, Reactivity ratio",

author = "C. Erbil and S. {\"O}zdemir and N. Uyanik",

year = "2000",

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doi = "10.1016/S0032-3861(99)00291-8",

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TY - JOUR

T1 - Determination of the monomer reactivity ratios for copolymerization of itaconic acid and acrylamide by conductometric titration method

AU - Erbil, C.

AU - Özdemir, S.

AU - Uyanik, N.

PY - 2000/2

Y1 - 2000/2

N2 - Composition of low conversion itaconic acid-acrylamide (IA-AAm) copolymers synthesized with solution polymerization in aqueous medium by using potassium persulfate under nitrogen atmosphere were determined by conductometric titration method. The results were evaluated by various linear and nonlinear methods. The monomer reactivity ratios were found to be rIA = 1.47 ± 0.03, rAAm = 0.76 ± 0.02 with Fineman-Ross, rIA = 1.25 ± 0.10, rAAm = 0.67 ± 0.05 with Kelen-Tudos, rIA = 1.65 ± 0.21, rAAm = 0.88 ± 0.08 with Tidwell-Mortimer methods. For this system, the analysis of results show that IA is a more reactive monomer in IA-AAm copolymerization.

AB - Composition of low conversion itaconic acid-acrylamide (IA-AAm) copolymers synthesized with solution polymerization in aqueous medium by using potassium persulfate under nitrogen atmosphere were determined by conductometric titration method. The results were evaluated by various linear and nonlinear methods. The monomer reactivity ratios were found to be rIA = 1.47 ± 0.03, rAAm = 0.76 ± 0.02 with Fineman-Ross, rIA = 1.25 ± 0.10, rAAm = 0.67 ± 0.05 with Kelen-Tudos, rIA = 1.65 ± 0.21, rAAm = 0.88 ± 0.08 with Tidwell-Mortimer methods. For this system, the analysis of results show that IA is a more reactive monomer in IA-AAm copolymerization.

KW - Acrylamide

KW - Itaconic acid

KW - Reactivity ratio

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U2 - 10.1016/S0032-3861(99)00291-8

DO - 10.1016/S0032-3861(99)00291-8

M3 - Article

AN - SCOPUS:0034142597

SN - 0032-3861

VL - 41

SP - 1391

EP - 1394

JO - Polymer

JF - Polymer

IS - 4

ER -

Determination of the monomer reactivity ratios for copolymerization of itaconic acid and acrylamide by conductometric titration method

Abstract

Keywords

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