Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer

Aysegul Cigdem Adiguzel; Fatih Cakar; Bahire Filiz Senkal; Ozlem Cankurtaran; Yesim Hepuzer Gursel; Ferdane Karaman

doi:10.2298/TSCI180912343A

Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer

Aysegul Cigdem Adiguzel, Fatih Cakar, Bahire Filiz Senkal, Ozlem Cankurtaran^*, Yesim Hepuzer Gursel, Ferdane Karaman

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The novel chalcone modified poly (styrene) based polymer (PVBC-DMAC) has been prepared and characterized. By using the inverse gas chromatography method, we determined glass transition temperature and surface properties of PVBCDMAC. The obtained glass transition temperature, T_g, is a good agree with the one obtained by differential scanning calorimetry. Also considering some isomeric alcohol and acetate solvents in the temperature range from 303.2 K to 353.2 K, we investigated the polymer selectivity. The parameters K_A (acidic) and K_D (basic) of the PVBC-DMAC surface were calculated. The obtained K_A, K_D values reflected that PVBC-DMAC surface has a basic character.

Original language	English
Pages (from-to)	S193-S202
Journal	Thermal Science
Volume	23
DOIs	https://doi.org/10.2298/TSCI180912343A
Publication status	Published - 2019

Bibliographical note

Publisher Copyright:
© 2019 Society of Thermal Engineers of Serbia.

Funding

This research has been supported by Yildiz Technical University Scientific Research Projects Coordination Department. Project Number: FDK-2018-3502.

Funders	Funder number
Yildiz Technical University Scientific Research Projects Coordination Department	FDK-2018-3502

Keywords

Chalcone modified poly (styrene) based polymer
Glass transition temperature
Inverse gas chromatography
Isomer solvent seperation
Surface properties

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10.2298/TSCI180912343A

Cite this

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title = "Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer",

abstract = "The novel chalcone modified poly (styrene) based polymer (PVBC-DMAC) has been prepared and characterized. By using the inverse gas chromatography method, we determined glass transition temperature and surface properties of PVBCDMAC. The obtained glass transition temperature, Tg, is a good agree with the one obtained by differential scanning calorimetry. Also considering some isomeric alcohol and acetate solvents in the temperature range from 303.2 K to 353.2 K, we investigated the polymer selectivity. The parameters KA (acidic) and KD (basic) of the PVBC-DMAC surface were calculated. The obtained KA, KD values reflected that PVBC-DMAC surface has a basic character.",

keywords = "Chalcone modified poly (styrene) based polymer, Glass transition temperature, Inverse gas chromatography, Isomer solvent seperation, Surface properties",

author = "Adiguzel, {Aysegul Cigdem} and Fatih Cakar and Senkal, {Bahire Filiz} and Ozlem Cankurtaran and Gursel, {Yesim Hepuzer} and Ferdane Karaman",

note = "Publisher Copyright: {\textcopyright} 2019 Society of Thermal Engineers of Serbia.",

year = "2019",

doi = "10.2298/TSCI180912343A",

language = "English",

volume = "23",

pages = "S193--S202",

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T1 - Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer

AU - Adiguzel, Aysegul Cigdem

AU - Cakar, Fatih

AU - Senkal, Bahire Filiz

AU - Cankurtaran, Ozlem

AU - Gursel, Yesim Hepuzer

AU - Karaman, Ferdane

PY - 2019

Y1 - 2019

N2 - The novel chalcone modified poly (styrene) based polymer (PVBC-DMAC) has been prepared and characterized. By using the inverse gas chromatography method, we determined glass transition temperature and surface properties of PVBCDMAC. The obtained glass transition temperature, Tg, is a good agree with the one obtained by differential scanning calorimetry. Also considering some isomeric alcohol and acetate solvents in the temperature range from 303.2 K to 353.2 K, we investigated the polymer selectivity. The parameters KA (acidic) and KD (basic) of the PVBC-DMAC surface were calculated. The obtained KA, KD values reflected that PVBC-DMAC surface has a basic character.

AB - The novel chalcone modified poly (styrene) based polymer (PVBC-DMAC) has been prepared and characterized. By using the inverse gas chromatography method, we determined glass transition temperature and surface properties of PVBCDMAC. The obtained glass transition temperature, Tg, is a good agree with the one obtained by differential scanning calorimetry. Also considering some isomeric alcohol and acetate solvents in the temperature range from 303.2 K to 353.2 K, we investigated the polymer selectivity. The parameters KA (acidic) and KD (basic) of the PVBC-DMAC surface were calculated. The obtained KA, KD values reflected that PVBC-DMAC surface has a basic character.

KW - Chalcone modified poly (styrene) based polymer

KW - Glass transition temperature

KW - Inverse gas chromatography

KW - Isomer solvent seperation

KW - Surface properties

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DO - 10.2298/TSCI180912343A

M3 - Article

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SN - 0354-9836

VL - 23

SP - S193-S202

JO - Thermal Science

JF - Thermal Science

ER -

Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer

Abstract

Bibliographical note

Funding

Keywords

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