Cyclic homo and block copolymers through sequential double click reactions

Hakan Durmaz; Aydan Dag; Gurkan Hizal; Umit Tunca

doi:10.1002/pola.24306

Cyclic homo and block copolymers through sequential double click reactions

Hakan Durmaz
, Aydan Dag
, Gurkan Hizal
, Umit Tunca^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Well-defined linear α-anthracene-ω-maleimide functionalized polystyrene (l-Anth-PS-MI) and linear α-alkyne-ω-male-imide functionalized poly(tert-butyl acrylate) (l-alkyne-PtBA-MI) homopolymers, and linear α-anthracene-ω-maleimide functionalized PS-b-PtBA (l-Anth-PS-b-PtBA-MI) and linear α-anthracene-ω-maleimide functionalized PS-b-poly(ε-caprolactone) (PCL) (l-Anth-PS-b-PCL-MI) block copolymers were obtained via combination of atom transfer radical polymerization (ATRP)/ring opening polymerization (ROP) and azide-alkyne click reaction strategy. Subsequently, these linear homo and block copolymers were efficiently clicked via Diels-Alder reaction to give their corresponding cyclic homo and block copolymers at reflux temperature of toluene for 48 h under 7-4 × 10^-5 M conditions.

Original language	English
Pages (from-to)	5083-5091
Number of pages	9
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	48
Issue number	22
DOIs	https://doi.org/10.1002/pola.24306
Publication status	Published - 15 Nov 2010

Keywords

azide-alkyne click reaction
cyclic block copolymer
cyclic homopolymer
Diels-Alder click reaction
triple detection GPC

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10.1002/pola.24306

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title = "Cyclic homo and block copolymers through sequential double click reactions",

abstract = "Well-defined linear α-anthracene-ω-maleimide functionalized polystyrene (l-Anth-PS-MI) and linear α-alkyne-ω-male-imide functionalized poly(tert-butyl acrylate) (l-alkyne-PtBA-MI) homopolymers, and linear α-anthracene-ω-maleimide functionalized PS-b-PtBA (l-Anth-PS-b-PtBA-MI) and linear α-anthracene-ω-maleimide functionalized PS-b-poly(ε-caprolactone) (PCL) (l-Anth-PS-b-PCL-MI) block copolymers were obtained via combination of atom transfer radical polymerization (ATRP)/ring opening polymerization (ROP) and azide-alkyne click reaction strategy. Subsequently, these linear homo and block copolymers were efficiently clicked via Diels-Alder reaction to give their corresponding cyclic homo and block copolymers at reflux temperature of toluene for 48 h under 7-4 × 10-5 M conditions.",

keywords = "azide-alkyne click reaction, cyclic block copolymer, cyclic homopolymer, Diels-Alder click reaction, triple detection GPC",

author = "Hakan Durmaz and Aydan Dag and Gurkan Hizal and Umit Tunca",

year = "2010",

month = nov,

day = "15",

doi = "10.1002/pola.24306",

language = "English",

volume = "48",

pages = "5083--5091",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

number = "22",

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TY - JOUR

T1 - Cyclic homo and block copolymers through sequential double click reactions

AU - Durmaz, Hakan

AU - Dag, Aydan

AU - Hizal, Gurkan

AU - Tunca, Umit

PY - 2010/11/15

Y1 - 2010/11/15

N2 - Well-defined linear α-anthracene-ω-maleimide functionalized polystyrene (l-Anth-PS-MI) and linear α-alkyne-ω-male-imide functionalized poly(tert-butyl acrylate) (l-alkyne-PtBA-MI) homopolymers, and linear α-anthracene-ω-maleimide functionalized PS-b-PtBA (l-Anth-PS-b-PtBA-MI) and linear α-anthracene-ω-maleimide functionalized PS-b-poly(ε-caprolactone) (PCL) (l-Anth-PS-b-PCL-MI) block copolymers were obtained via combination of atom transfer radical polymerization (ATRP)/ring opening polymerization (ROP) and azide-alkyne click reaction strategy. Subsequently, these linear homo and block copolymers were efficiently clicked via Diels-Alder reaction to give their corresponding cyclic homo and block copolymers at reflux temperature of toluene for 48 h under 7-4 × 10-5 M conditions.

AB - Well-defined linear α-anthracene-ω-maleimide functionalized polystyrene (l-Anth-PS-MI) and linear α-alkyne-ω-male-imide functionalized poly(tert-butyl acrylate) (l-alkyne-PtBA-MI) homopolymers, and linear α-anthracene-ω-maleimide functionalized PS-b-PtBA (l-Anth-PS-b-PtBA-MI) and linear α-anthracene-ω-maleimide functionalized PS-b-poly(ε-caprolactone) (PCL) (l-Anth-PS-b-PCL-MI) block copolymers were obtained via combination of atom transfer radical polymerization (ATRP)/ring opening polymerization (ROP) and azide-alkyne click reaction strategy. Subsequently, these linear homo and block copolymers were efficiently clicked via Diels-Alder reaction to give their corresponding cyclic homo and block copolymers at reflux temperature of toluene for 48 h under 7-4 × 10-5 M conditions.

KW - azide-alkyne click reaction

KW - cyclic block copolymer

KW - cyclic homopolymer

KW - Diels-Alder click reaction

KW - triple detection GPC

UR - https://www.scopus.com/pages/publications/78649582249

U2 - 10.1002/pola.24306

DO - 10.1002/pola.24306

M3 - Article

AN - SCOPUS:78649582249

SN - 0887-624X

VL - 48

SP - 5083

EP - 5091

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 22

ER -

Cyclic homo and block copolymers through sequential double click reactions

Abstract

Keywords

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