TY - JOUR
T1 - Crosslinked poly(styrenesulfonamide) with iminoacetic acid chelating groups for hard-water treatment
AU - Biçak, Niyazi
AU - Şenkal, Bahire Filiz
AU - Yarbaş, Tuǧrul
PY - 1998/12
Y1 - 1998/12
N2 - Chlorosulfonated polystyrene-DVB (10%) copolymer (in beads form, 720-840 μm) has been modified with triethylenetetramine (TETA) to give the corresponding polymeric sulfonamide. By treating with the potassium salt of chloroacetic acid in water, amino groups of the polymer have been carboxymethylated almost quantitatively. The resulting material with iminoacetic acid pendant groups has very efficient chelating ability for Ca(II) and Mg(II) ions in ppm levels. The chelating polymer can be regenerated ten times by acid leaching without losing its original reactivity. It is suitable for removal of calcium and magnesium ions to supply soft water.
AB - Chlorosulfonated polystyrene-DVB (10%) copolymer (in beads form, 720-840 μm) has been modified with triethylenetetramine (TETA) to give the corresponding polymeric sulfonamide. By treating with the potassium salt of chloroacetic acid in water, amino groups of the polymer have been carboxymethylated almost quantitatively. The resulting material with iminoacetic acid pendant groups has very efficient chelating ability for Ca(II) and Mg(II) ions in ppm levels. The chelating polymer can be regenerated ten times by acid leaching without losing its original reactivity. It is suitable for removal of calcium and magnesium ions to supply soft water.
UR - http://www.scopus.com/inward/record.url?scp=0037774189&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1521-3935(19981201)199:12<2731::AID-MACP2731>3.3.CO;2-L
DO - 10.1002/(SICI)1521-3935(19981201)199:12<2731::AID-MACP2731>3.3.CO;2-L
M3 - Article
AN - SCOPUS:0037774189
SN - 1022-1352
VL - 199
SP - 2731
EP - 2735
JO - Macromolecular Chemistry and Physics
JF - Macromolecular Chemistry and Physics
IS - 12
ER -