Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Elif Keskin; Nesrin Köken; Nilgün Kızılcan; Ahmet Akar

doi:10.1080/25740881.2023.2250863

Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Elif Keskin, Nesrin Köken^*, Nilgün Kızılcan, Ahmet Akar

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

Original language	English
Pages (from-to)	2030-2042
Number of pages	13
Journal	Polymer-Plastics Technology and Materials
Volume	62
Issue number	15
DOIs	https://doi.org/10.1080/25740881.2023.2250863
Publication status	Published - 2023

Bibliographical note

Publisher Copyright:
© 2023 Taylor & Francis.

Keywords

Flame-retardant
nanofiber
phosphorous
polyacrylonitrile
vinyl phosphonic acid

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10.1080/25740881.2023.2250863

Cite this

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title = "Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber",

abstract = "Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.",

keywords = "Flame-retardant, nanofiber, phosphorous, polyacrylonitrile, vinyl phosphonic acid",

author = "Elif Keskin and Nesrin K{\"o}ken and Nilg{\"u}n Kızılcan and Ahmet Akar",

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doi = "10.1080/25740881.2023.2250863",

language = "English",

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pages = "2030--2042",

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T1 - Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

AU - Keskin, Elif

AU - Köken, Nesrin

AU - Kızılcan, Nilgün

AU - Akar, Ahmet

PY - 2023

Y1 - 2023

N2 - Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

AB - Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

KW - Flame-retardant

KW - nanofiber

KW - phosphorous

KW - polyacrylonitrile

KW - vinyl phosphonic acid

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U2 - 10.1080/25740881.2023.2250863

DO - 10.1080/25740881.2023.2250863

M3 - Article

AN - SCOPUS:85168885488

SN - 2574-0881

VL - 62

SP - 2030

EP - 2042

JO - Polymer-Plastics Technology and Materials

JF - Polymer-Plastics Technology and Materials

IS - 15

ER -

Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Abstract

Bibliographical note

Keywords

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