Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole

F. Yilmaz; O. Sel; Y. Guner; L. Toppare; Y. Hepuzer; Y. Yagci

doi:10.1081/MA-120028475

Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole

F. Yilmaz
, O. Sel
, Y. Guner
, L. Toppare^*
, Y. Hepuzer
, Y. Yagci

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University
Middle East Technical University

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

This paper reports on the synthesis of conducting polypyrrole and polythiophene grafted block copolymers of methylmethacrylate (MMA) and 3-methylthienylmethacrylate (MTM) by a multi-step process. For this purpose, block copolymers of MMA and MTM were prepared by controlled radical polymerization using 1,1-diphenylethene (DPE). Subsequently, polypyrrole and polythiophene sequences were grafted onto these block copolymers by constant potential electrolysis.

Original language	English
Pages (from-to)	401-418
Number of pages	18
Journal	Journal of Macromolecular Science, Part A: Pure and Applied Chemistry
Volume	41
Issue number	4
DOIs	https://doi.org/10.1081/MA-120028475
Publication status	Published - Apr 2004

Keywords

1,1-Diphenylethene
Conducting copolymers
Electrochemical grafting
Poly(methylmethacrylate-b-3-methylthienylmethacrylate)

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10.1081/MA-120028475

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title = "Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole",

abstract = "This paper reports on the synthesis of conducting polypyrrole and polythiophene grafted block copolymers of methylmethacrylate (MMA) and 3-methylthienylmethacrylate (MTM) by a multi-step process. For this purpose, block copolymers of MMA and MTM were prepared by controlled radical polymerization using 1,1-diphenylethene (DPE). Subsequently, polypyrrole and polythiophene sequences were grafted onto these block copolymers by constant potential electrolysis.",

keywords = "1,1-Diphenylethene, Conducting copolymers, Electrochemical grafting, Poly(methylmethacrylate-b-3-methylthienylmethacrylate)",

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T1 - Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole

AU - Yilmaz, F.

AU - Sel, O.

AU - Guner, Y.

AU - Toppare, L.

AU - Hepuzer, Y.

AU - Yagci, Y.

PY - 2004/4

Y1 - 2004/4

N2 - This paper reports on the synthesis of conducting polypyrrole and polythiophene grafted block copolymers of methylmethacrylate (MMA) and 3-methylthienylmethacrylate (MTM) by a multi-step process. For this purpose, block copolymers of MMA and MTM were prepared by controlled radical polymerization using 1,1-diphenylethene (DPE). Subsequently, polypyrrole and polythiophene sequences were grafted onto these block copolymers by constant potential electrolysis.

AB - This paper reports on the synthesis of conducting polypyrrole and polythiophene grafted block copolymers of methylmethacrylate (MMA) and 3-methylthienylmethacrylate (MTM) by a multi-step process. For this purpose, block copolymers of MMA and MTM were prepared by controlled radical polymerization using 1,1-diphenylethene (DPE). Subsequently, polypyrrole and polythiophene sequences were grafted onto these block copolymers by constant potential electrolysis.

KW - 1,1-Diphenylethene

KW - Conducting copolymers

KW - Electrochemical grafting

KW - Poly(methylmethacrylate-b-3-methylthienylmethacrylate)

UR - https://www.scopus.com/pages/publications/1842584767

U2 - 10.1081/MA-120028475

DO - 10.1081/MA-120028475

M3 - Article

AN - SCOPUS:1842584767

SN - 1060-1325

VL - 41

SP - 401

EP - 418

JO - Journal of Macromolecular Science, Part A: Pure and Applied Chemistry

JF - Journal of Macromolecular Science, Part A: Pure and Applied Chemistry

IS - 4

ER -

Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole

Abstract

Keywords

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