Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator

Tuba Çakır Çanak; Ersin Serhatl

Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator

Tuba Çakır Çanak, Ersin Serhatl

Department of Chemistry

Istanbul Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The synthesis of polymethylmethacrylate (pMMA) was realized with newly synthesized difunctional initiator, bis[4-(β-(2-bromopropanoate) ethoxy)phenyl]sulphone (BrEPS) in the presence of copper bromide (CuBr) and N, N, N’, N’’, N’’-pentamethyl-diethylenetriamine (PMDETA) by using atom transfer radical polymerization (ATRP). Sulphone group containing initiator was prepared by esterification of bis[4-(β-hydroxyethoxy)phenyl] sulfone (HEPS). Both initiator and polymers were characterized by 1H-NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The ATRP was supported by an increase in the molecular weight of the forming polymers and also by their monomodal molecular weight distribution. Pendulum hardness tests on films of synthesized polymers indicated higher degree of hardness than that of pure pMMA.

Original language	English
Title of host publication	Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015
Editors	Jamal Chaouki, Yuyuan Zhao
Publisher	Avestia Publishing
ISBN (Print)	9781927877173
Publication status	Published - 2015
Event	World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015 - Barcelona, Spain Duration: 20 Jul 2015 → 21 Jul 2015

Publication series

Name	Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering
ISSN (Electronic)	2369-8136

Conference

Conference	World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015
Country/Territory	Spain
City	Barcelona
Period	20/07/15 → 21/07/15

Bibliographical note

Publisher Copyright:
© 2015, Avestia Publishing. All rights reserved.

Keywords

ATRP
Initiator
Polymethylmethacrylate
Sulfone containing

Cite this

Çanak, Tuba Çakır ; Serhatl, Ersin. / Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator. Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015. editor / Jamal Chaouki ; Yuyuan Zhao. Avestia Publishing, 2015. (Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering).

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title = "Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator",

abstract = "The synthesis of polymethylmethacrylate (pMMA) was realized with newly synthesized difunctional initiator, bis[4-(β-(2-bromopropanoate) ethoxy)phenyl]sulphone (BrEPS) in the presence of copper bromide (CuBr) and N, N, N{\textquoteright}, N{\textquoteright}{\textquoteright}, N{\textquoteright}{\textquoteright}-pentamethyl-diethylenetriamine (PMDETA) by using atom transfer radical polymerization (ATRP). Sulphone group containing initiator was prepared by esterification of bis[4-(β-hydroxyethoxy)phenyl] sulfone (HEPS). Both initiator and polymers were characterized by 1H-NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The ATRP was supported by an increase in the molecular weight of the forming polymers and also by their monomodal molecular weight distribution. Pendulum hardness tests on films of synthesized polymers indicated higher degree of hardness than that of pure pMMA.",

keywords = "ATRP, Initiator, Polymethylmethacrylate, Sulfone containing",

author = "{\c C}anak, {Tuba {\c C}akır} and Ersin Serhatl",

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year = "2015",

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series = "Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering",

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Çanak, TÇ & Serhatl, E 2015, Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator. in J Chaouki & Y Zhao (eds), Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015. Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering, Avestia Publishing, World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015, Barcelona, Spain, 20/07/15.

Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator. / Çanak, Tuba Çakır; Serhatl, Ersin.
Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015. ed. / Jamal Chaouki; Yuyuan Zhao. Avestia Publishing, 2015. (Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator

AU - Çanak, Tuba Çakır

AU - Serhatl, Ersin

PY - 2015

Y1 - 2015

N2 - The synthesis of polymethylmethacrylate (pMMA) was realized with newly synthesized difunctional initiator, bis[4-(β-(2-bromopropanoate) ethoxy)phenyl]sulphone (BrEPS) in the presence of copper bromide (CuBr) and N, N, N’, N’’, N’’-pentamethyl-diethylenetriamine (PMDETA) by using atom transfer radical polymerization (ATRP). Sulphone group containing initiator was prepared by esterification of bis[4-(β-hydroxyethoxy)phenyl] sulfone (HEPS). Both initiator and polymers were characterized by 1H-NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The ATRP was supported by an increase in the molecular weight of the forming polymers and also by their monomodal molecular weight distribution. Pendulum hardness tests on films of synthesized polymers indicated higher degree of hardness than that of pure pMMA.

AB - The synthesis of polymethylmethacrylate (pMMA) was realized with newly synthesized difunctional initiator, bis[4-(β-(2-bromopropanoate) ethoxy)phenyl]sulphone (BrEPS) in the presence of copper bromide (CuBr) and N, N, N’, N’’, N’’-pentamethyl-diethylenetriamine (PMDETA) by using atom transfer radical polymerization (ATRP). Sulphone group containing initiator was prepared by esterification of bis[4-(β-hydroxyethoxy)phenyl] sulfone (HEPS). Both initiator and polymers were characterized by 1H-NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The ATRP was supported by an increase in the molecular weight of the forming polymers and also by their monomodal molecular weight distribution. Pendulum hardness tests on films of synthesized polymers indicated higher degree of hardness than that of pure pMMA.

KW - ATRP

KW - Initiator

KW - Polymethylmethacrylate

KW - Sulfone containing

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M3 - Conference contribution

AN - SCOPUS:85146651207

SN - 9781927877173

T3 - Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering

BT - Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015

A2 - Chaouki, Jamal

A2 - Zhao, Yuyuan

PB - Avestia Publishing

T2 - World Congress on Mechanical, Chemical, and Material Engineering, MCM 2015

Y2 - 20 July 2015 through 21 July 2015

ER -

Controlled Polymerization of Polymethylmethacrylate with Sulfone Containing Initiator

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