Controlled electroinduced polymerization of methyl methacrylate in the presence of catalytic amount of cerium(IV)

A. Sezai Saraç; Serife Özkara; Belkis Ustamehmetoglu; Esma Sezer

doi:10.1081/MA-120017260

Controlled electroinduced polymerization of methyl methacrylate in the presence of catalytic amount of cerium(IV)

A. Sezai Saraç^*, Serife Özkara, Belkis Ustamehmetoglu, Esma Sezer

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Controlled electroinduced methyl methacrylate (MMA) polymerization was realized with high yields and in short period of times by the use of catalytic amount of cerium(IV) [Ce(IV)] which is continuously regenerated. Progress of polymerization was followed electrochemically and spectrophotometrically. Resulting polymers were characterized by FT-IR and UV-Visible spectrometry and molecular weight of polymers were determined by GPC and viscometric measurements.

Original language	English
Pages (from-to)	193-207
Number of pages	15
Journal	Journal of Macromolecular Science - Pure and Applied Chemistry
Volume	40 A
Issue number	2
DOIs	https://doi.org/10.1081/MA-120017260
Publication status	Published - Feb 2003

Keywords

Ceric salt
Electrocatalytic polymerization
Electroinduced polymerization
Polymethylmethacrylate

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abstract = "Controlled electroinduced methyl methacrylate (MMA) polymerization was realized with high yields and in short period of times by the use of catalytic amount of cerium(IV) [Ce(IV)] which is continuously regenerated. Progress of polymerization was followed electrochemically and spectrophotometrically. Resulting polymers were characterized by FT-IR and UV-Visible spectrometry and molecular weight of polymers were determined by GPC and viscometric measurements.",

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AU - Saraç, A. Sezai

AU - Özkara, Serife

AU - Ustamehmetoglu, Belkis

AU - Sezer, Esma

PY - 2003/2

Y1 - 2003/2

N2 - Controlled electroinduced methyl methacrylate (MMA) polymerization was realized with high yields and in short period of times by the use of catalytic amount of cerium(IV) [Ce(IV)] which is continuously regenerated. Progress of polymerization was followed electrochemically and spectrophotometrically. Resulting polymers were characterized by FT-IR and UV-Visible spectrometry and molecular weight of polymers were determined by GPC and viscometric measurements.

AB - Controlled electroinduced methyl methacrylate (MMA) polymerization was realized with high yields and in short period of times by the use of catalytic amount of cerium(IV) [Ce(IV)] which is continuously regenerated. Progress of polymerization was followed electrochemically and spectrophotometrically. Resulting polymers were characterized by FT-IR and UV-Visible spectrometry and molecular weight of polymers were determined by GPC and viscometric measurements.

KW - Ceric salt

KW - Electrocatalytic polymerization

KW - Electroinduced polymerization

KW - Polymethylmethacrylate

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U2 - 10.1081/MA-120017260

DO - 10.1081/MA-120017260

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AN - SCOPUS:0037296286

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JO - Journal of Macromolecular Science - Pure and Applied Chemistry

JF - Journal of Macromolecular Science - Pure and Applied Chemistry

IS - 2

ER -

Controlled electroinduced polymerization of methyl methacrylate in the presence of catalytic amount of cerium(IV)

Abstract

Keywords

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