Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

Yusuf Guner; Levent Toppare; Yesim Hepuzer; Yusuf Yagci

doi:10.1016/j.eurpolymj.2004.03.029

Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

Yusuf Guner, Levent Toppare^*, Yesim Hepuzer, Yusuf Yagci

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).

Original language	English
Pages (from-to)	1799-1806
Number of pages	8
Journal	European Polymer Journal
Volume	40
Issue number	8
DOIs	https://doi.org/10.1016/j.eurpolymj.2004.03.029
Publication status	Published - Aug 2004

Funding

This work was supported by DPT2003K120920-02, METU BAP-2003-01-03-02, Istanbul Technical University Research Fund and Turkish Academy of Sciences (TUBA).

Funders	Funder number
METU	BAP-2003-01-03-02
TUBA
Türkiye Bilimler Akademisi
Istanbul Teknik Üniversitesi

Keywords

Conducting copolymers
Electrochemical polymerization
Graft copolymers

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10.1016/j.eurpolymj.2004.03.029

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title = "Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate",

abstract = "Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).",

keywords = "Conducting copolymers, Electrochemical polymerization, Graft copolymers",

author = "Yusuf Guner and Levent Toppare and Yesim Hepuzer and Yusuf Yagci",

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T1 - Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

AU - Guner, Yusuf

AU - Toppare, Levent

AU - Hepuzer, Yesim

AU - Yagci, Yusuf

PY - 2004/8

Y1 - 2004/8

N2 - Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).

AB - Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).

KW - Conducting copolymers

KW - Electrochemical polymerization

KW - Graft copolymers

UR - https://www.scopus.com/pages/publications/3042734663

U2 - 10.1016/j.eurpolymj.2004.03.029

DO - 10.1016/j.eurpolymj.2004.03.029

M3 - Article

AN - SCOPUS:3042734663

SN - 0014-3057

VL - 40

SP - 1799

EP - 1806

JO - European Polymer Journal

JF - European Polymer Journal

IS - 8

ER -

Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

Abstract

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