Comparison of oxidation behavior of nitride based hard ceramic thin film coatings using thermal analysis techniques

N. Solak*, F. Üstel, S. Aydin, M. Ürgen, A. F. Cakir

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

CrN, TiN and Ti-B-N coatings were deposited onto H13 hot-working tool steel and alumina substrates by arc-PVD. The coatings were characterized with respect to their mechanical and structural properties. Oxidation behavior of the coatings on alumina substrates was investigated by TG/DTA. Samples coated on H13 substrates were oxidized in a tube furnace under atmospheric conditions at specific temperatures determined from TG/DTA tests of the same coatings deposited on alumina substrates. The oxide scale morphology was characterized by scanning electron microscopy and X-ray diffraction. Oxide scale thickness change and TG data were used to calculate oxidation reaction activation energies. It was determined that boron addition into TiN coating improves not only mechanical properties but also oxidation resistance. Depending on the substrate material different oxidation activation energy values for the TiN and Ti-B-N coatings were determined revealing the importance of film morphology on oxidation resistance.

Original languageEnglish
Title of host publicationSohn International Symposium
Subtitle of host publicationAdvanced Processing of Metals and Materials - Proceedings of the International Symposium
Pages253-262
Number of pages10
Publication statusPublished - 2006
Event2006 TMS Fall Extraction and Processing Division: Sohn International Symposium - San Diego, CA, United States
Duration: 27 Aug 200631 Aug 2006

Publication series

Name2006 TMS Fall Extraction and Processing Division: Sohn International Symposium
Volume3

Conference

Conference2006 TMS Fall Extraction and Processing Division: Sohn International Symposium
Country/TerritoryUnited States
CitySan Diego, CA
Period27/08/0631/08/06

Keywords

  • CrN
  • Oxidation behavior
  • Thermal analysis
  • Ti-B-N
  • TiN

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