Comparative Thermodynamic Prediction of Integral Properties of Six Component, Quaternary, and Ternary Systems

Ali Dogan, Hüseyin Arslan*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

In the present study, the enthalpies of mixing associated with the liquid phase in Ni-Cr-Co-Al-Ti-Cu, Au-In-Sn-Zn, and In-Pd-Sn systems at a temperature of 2000 K (1727 °C) through the six components, ternary, and quaternary geometric models are calculated. The values calculated from different geometric models are compared with those obtained in the experiments. In this respect, the results of some thermodynamic prediction methods were applied to the six-component Ni-Cr-Co-Al-Ti-Cu system, the quaternary alloy Au-In0.45-Sn0.45-Zn0.1, and the subsystem ternary alloy In-Pd-Sn in the present study in order to analytically determine the integral properties associated with the six-component alloy systems in the liquid phase. The Chou’s general solution model and the traditional models of Toop, Colinet, Muggianu, and Kohler were included in the calculation for comparison and discussion. A comparison among the results of the models and experiments carried out for ternary and quaternary systems displays good mutual agreement.

Original languageEnglish
Pages (from-to)3753-3760
Number of pages8
JournalMetallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
Volume46
Issue number8
DOIs
Publication statusPublished - 25 Aug 2015
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2015, The Minerals, Metals & Materials Society and ASM International.

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