Combining S-DADPS monomer and halloysite nanotube for fabrication superior nanofiltration membrane

Türkan Ormancı-Acar; Sevde Korkut; Basak Keskin; Meltem Ağtaş; C. Erdinç Taş; Öykü Mutlu-Salmanlı; Türker Türken; Yusuf Z. Menceloğlu; Serkan Ünal; İsmail Koyuncu

doi:10.1016/j.polymer.2022.125174

Combining S-DADPS monomer and halloysite nanotube for fabrication superior nanofiltration membrane

Türkan Ormancı-Acar, Sevde Korkut, Basak Keskin, Meltem Ağtaş, C. Erdinç Taş, Öykü Mutlu-Salmanlı, Türker Türken, Yusuf Z. Menceloğlu, Serkan Ünal, İsmail Koyuncu^*

^*Corresponding author for this work

Department of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In this paper, halloysite nanotubes (HNTs) and disodium-3-3′-disulfone-4-4′-dichlorodiphenylsulfone (S-DADPS) incorporated membranes designed to create a superior nanofiltration membrane. Interfacial polymerization technique was used for the fabrication process and key characterization tests such as contact angle, zeta potential, Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy Spectrum (FT-IR) were conducted prior to salt and dye performances tests. Two different dyes, setazol red and reactive orange of 100 ppm, and two different salt solutions, MgSO₄ and NaCl of 1000 ppm were used to determine the performances. Consequently, MS-0.01 membrane was selected as best performed membrane, the addition of hydrophilic 0.01% of HNTs and 80% of S-DADPS monomer formed the best recipe to produce a thin film nanocomposite NF membrane. Lastly, pH and temperature resistance tests were performed to further investigate the performance losses of the selected membrane.

Original language	English
Article number	125174
Journal	Polymer
Volume	255
DOIs	https://doi.org/10.1016/j.polymer.2022.125174
Publication status	Published - 22 Aug 2022

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Ltd

Funding

This study was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) under the grant agreement number 113Y350/113Y371 and Istanbul University-Cerrahpaşa Scientific Research Projects ( 52369 , 2015 ).

Funders	Funder number
Istanbul University-Cerrahpaşa Scientific Research Projects	52369
Türkiye Bilimsel ve Teknolojik Araştırma Kurumu	113Y350/113Y371

Keywords

Disulfonated diamine monomer
Dye removal
Halloysite nanotubes
Interfacial polymerization
Nanofiltration

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10.1016/j.polymer.2022.125174

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title = "Combining S-DADPS monomer and halloysite nanotube for fabrication superior nanofiltration membrane",

abstract = "In this paper, halloysite nanotubes (HNTs) and disodium-3-3′-disulfone-4-4′-dichlorodiphenylsulfone (S-DADPS) incorporated membranes designed to create a superior nanofiltration membrane. Interfacial polymerization technique was used for the fabrication process and key characterization tests such as contact angle, zeta potential, Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy Spectrum (FT-IR) were conducted prior to salt and dye performances tests. Two different dyes, setazol red and reactive orange of 100 ppm, and two different salt solutions, MgSO4 and NaCl of 1000 ppm were used to determine the performances. Consequently, MS-0.01 membrane was selected as best performed membrane, the addition of hydrophilic 0.01% of HNTs and 80% of S-DADPS monomer formed the best recipe to produce a thin film nanocomposite NF membrane. Lastly, pH and temperature resistance tests were performed to further investigate the performance losses of the selected membrane.",

keywords = "Disulfonated diamine monomer, Dye removal, Halloysite nanotubes, Interfacial polymerization, Nanofiltration",

author = "T{\"u}rkan Ormancı-Acar and Sevde Korkut and Basak Keskin and Meltem Ağta{\c s} and Ta{\c s}, {C. Erdin{\c c}} and {\"O}yk{\"u} Mutlu-Salmanlı and T{\"u}rker T{\"u}rken and Menceloğlu, {Yusuf Z.} and Serkan {\"U}nal and İsmail Koyuncu",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",

year = "2022",

month = aug,

day = "22",

doi = "10.1016/j.polymer.2022.125174",

language = "English",

volume = "255",

journal = "Polymer",

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T1 - Combining S-DADPS monomer and halloysite nanotube for fabrication superior nanofiltration membrane

AU - Ormancı-Acar, Türkan

AU - Korkut, Sevde

AU - Keskin, Basak

AU - Ağtaş, Meltem

AU - Taş, C. Erdinç

AU - Mutlu-Salmanlı, Öykü

AU - Türken, Türker

AU - Menceloğlu, Yusuf Z.

AU - Ünal, Serkan

AU - Koyuncu, İsmail

PY - 2022/8/22

Y1 - 2022/8/22

N2 - In this paper, halloysite nanotubes (HNTs) and disodium-3-3′-disulfone-4-4′-dichlorodiphenylsulfone (S-DADPS) incorporated membranes designed to create a superior nanofiltration membrane. Interfacial polymerization technique was used for the fabrication process and key characterization tests such as contact angle, zeta potential, Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy Spectrum (FT-IR) were conducted prior to salt and dye performances tests. Two different dyes, setazol red and reactive orange of 100 ppm, and two different salt solutions, MgSO4 and NaCl of 1000 ppm were used to determine the performances. Consequently, MS-0.01 membrane was selected as best performed membrane, the addition of hydrophilic 0.01% of HNTs and 80% of S-DADPS monomer formed the best recipe to produce a thin film nanocomposite NF membrane. Lastly, pH and temperature resistance tests were performed to further investigate the performance losses of the selected membrane.

AB - In this paper, halloysite nanotubes (HNTs) and disodium-3-3′-disulfone-4-4′-dichlorodiphenylsulfone (S-DADPS) incorporated membranes designed to create a superior nanofiltration membrane. Interfacial polymerization technique was used for the fabrication process and key characterization tests such as contact angle, zeta potential, Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy Spectrum (FT-IR) were conducted prior to salt and dye performances tests. Two different dyes, setazol red and reactive orange of 100 ppm, and two different salt solutions, MgSO4 and NaCl of 1000 ppm were used to determine the performances. Consequently, MS-0.01 membrane was selected as best performed membrane, the addition of hydrophilic 0.01% of HNTs and 80% of S-DADPS monomer formed the best recipe to produce a thin film nanocomposite NF membrane. Lastly, pH and temperature resistance tests were performed to further investigate the performance losses of the selected membrane.

KW - Disulfonated diamine monomer

KW - Dye removal

KW - Halloysite nanotubes

KW - Interfacial polymerization

KW - Nanofiltration

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DO - 10.1016/j.polymer.2022.125174

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JO - Polymer

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Combining S-DADPS monomer and halloysite nanotube for fabrication superior nanofiltration membrane

Abstract

Bibliographical note

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Keywords

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