Combining brown titanium dioxide with BiOBr and AgBr nanoparticles using a facile one-pot procedure to promote visible-light photocatalytic performance

Arezou Saadati, Aziz Habibi-Yangjeh*, Solmaz Feizpoor, Ramazan Keyikoglu, Alireza Khataee

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

The utilization of visible-light-responsive photocatalysts has received wide attention for the remediation of water pollution. Herein, BiOBr and AgBr nanoparticles were anchored on brown TiO2 to fabricate ternary TiO2-x/BiOBr/AgBr (named as TOx/BiOBr/AgBr) nanocomposites via a facile one-pot refluxing approach. The visible-light photocatalytic efficiencies were determined by elimination of tetracycline, methyl orange, fuchsine, and Rhodamine B. Ternary TOx/BiOBr/AgBr photocatalysts showed remarkable capability in the removal of aforesaid pollutants. The highest photocatalytic capability was related to the TOx/BiOBr/AgBr (20%) nanocomposite, which was 21.4, 211, 45.6, and 16.2 times as much as the TiO2 and 4.9, 22, 2.8, and 8.7-folds higher than the TiO2-x in photodegradation of methyl orange, Rhodamine B, tetracycline, and fuchsine pollutants, respectively. The enhanced photocatalytic performance for the ternary nanocomposite comes from the generation of oxygen vacancies on TiO2 and effective transfer of charge carriers through formation of p-n-n heterojunctions. Also, the TOx/BiOBr/AgBr (20%) sample manifested good photostability. This work offers that the ternary TOx/BiOBr/AgBr (20%) photocatalyst could be a fascinating photocatalyst for the remediation of water pollution.

Original languageEnglish
Article number114034
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume431
DOIs
Publication statusPublished - 1 Oct 2022
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2022 Elsevier B.V.

Keywords

  • Brown TiO
  • Photocatalytic efficiency
  • Tetracycline
  • TiO/BiOBr/AgBr
  • Water pollutants

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