Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control

Emre Ozdemir; Yusuf Alcay; Ozgur Yavuz; Mustafa Semih Yildirim; Hulya Aribuga; Utku Ertugral; Kerem Kaya; Ismail Yilmaz

doi:10.1016/j.talanta.2023.124660

Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control

Emre Ozdemir, Yusuf Alcay, Ozgur Yavuz, Mustafa Semih Yildirim, Hulya Aribuga, Utku Ertugral, Kerem Kaya, Ismail Yilmaz^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Detection of bisulfite (HSO₃⁻) in food and beverages has vital importance because the excessive amount leads to ill effects on the human body. Colorimetric and fluorometric chromenylium-cyanine-based chemosensor CyR was synthesized and applied for high selective and sensitive analysis of HSO₃⁻ in red wine, rose wine and, granulated sugar with high recovery ranges and very fast response time without any interference from other competitive species. The limits of detection (LOD) for the UV–Vis and fluorescence titrations were found as 11.5 μM and 3.77 μM, respectively. The on-site and very rapid methods based on paper strips and smartphone which depend on the color changes from yellow to green have been successfully developed to analyze HSO₃⁻ concentration (10⁻⁵-10⁻¹ M for paper strip and 163–1205 μM for smartphone). CyR and the bisulfite-adduct formed in the nucleophilic addition reaction with HSO₃⁻ were verified by FT-IR, ¹H NMR, and MALDI-TOF results as well as Single-Crystal X-Ray Crystallography for CyR.

Original language	English
Article number	124660
Journal	Talanta
Volume	261
DOIs	https://doi.org/10.1016/j.talanta.2023.124660
Publication status	Published - 15 Aug 2023

Bibliographical note

Publisher Copyright:
© 2023 Elsevier B.V.

Funding

This work was supported by Istanbul Technical University (BAP, Project no: 43645 ).

Funders	Funder number
Istanbul Teknik Üniversitesi
Bilimsel Araştırma Projeleri Birimi, İstanbul Teknik Üniversitesi	43645

Keywords

Bisulfite-probe
Chromenylium-cyanine
Colorimetric
Fluorometric
Near-infrared
Smartphone

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Istanbul Technical University Reports Findings in Science (Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site ...)
Yilmaz, I.
5/06/23
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Ozdemir, E., Alcay, Y., Yavuz, O., Yildirim, M. S., Aribuga, H., Ertugral, U., Kaya, K., & Yilmaz, I. (2023). Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control. Talanta, 261, Article 124660. https://doi.org/10.1016/j.talanta.2023.124660

@article{c124626c6ac248a7a1a89ba384c00724,

title = "Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control",

abstract = "Detection of bisulfite (HSO3−) in food and beverages has vital importance because the excessive amount leads to ill effects on the human body. Colorimetric and fluorometric chromenylium-cyanine-based chemosensor CyR was synthesized and applied for high selective and sensitive analysis of HSO3− in red wine, rose wine and, granulated sugar with high recovery ranges and very fast response time without any interference from other competitive species. The limits of detection (LOD) for the UV–Vis and fluorescence titrations were found as 11.5 μM and 3.77 μM, respectively. The on-site and very rapid methods based on paper strips and smartphone which depend on the color changes from yellow to green have been successfully developed to analyze HSO3− concentration (10−5-10−1 M for paper strip and 163–1205 μM for smartphone). CyR and the bisulfite-adduct formed in the nucleophilic addition reaction with HSO3− were verified by FT-IR, 1H NMR, and MALDI-TOF results as well as Single-Crystal X-Ray Crystallography for CyR.",

keywords = "Bisulfite-probe, Chromenylium-cyanine, Colorimetric, Fluorometric, Near-infrared, Smartphone",

author = "Emre Ozdemir and Yusuf Alcay and Ozgur Yavuz and Yildirim, {Mustafa Semih} and Hulya Aribuga and Utku Ertugral and Kerem Kaya and Ismail Yilmaz",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

year = "2023",

month = aug,

day = "15",

doi = "10.1016/j.talanta.2023.124660",

language = "English",

volume = "261",

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Ozdemir, E, Alcay, Y, Yavuz, O, Yildirim, MS, Aribuga, H, Ertugral, U, Kaya, K & Yilmaz, I 2023, 'Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control', Talanta, vol. 261, 124660. https://doi.org/10.1016/j.talanta.2023.124660

Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control. / Ozdemir, Emre; Alcay, Yusuf; Yavuz, Ozgur et al.
In: Talanta, Vol. 261, 124660, 15.08.2023.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor

T2 - Smartphone and paper strip applications for on-site food and beverages control

AU - Ozdemir, Emre

AU - Alcay, Yusuf

AU - Yavuz, Ozgur

AU - Yildirim, Mustafa Semih

AU - Aribuga, Hulya

AU - Ertugral, Utku

AU - Kaya, Kerem

AU - Yilmaz, Ismail

PY - 2023/8/15

Y1 - 2023/8/15

N2 - Detection of bisulfite (HSO3−) in food and beverages has vital importance because the excessive amount leads to ill effects on the human body. Colorimetric and fluorometric chromenylium-cyanine-based chemosensor CyR was synthesized and applied for high selective and sensitive analysis of HSO3− in red wine, rose wine and, granulated sugar with high recovery ranges and very fast response time without any interference from other competitive species. The limits of detection (LOD) for the UV–Vis and fluorescence titrations were found as 11.5 μM and 3.77 μM, respectively. The on-site and very rapid methods based on paper strips and smartphone which depend on the color changes from yellow to green have been successfully developed to analyze HSO3− concentration (10−5-10−1 M for paper strip and 163–1205 μM for smartphone). CyR and the bisulfite-adduct formed in the nucleophilic addition reaction with HSO3− were verified by FT-IR, 1H NMR, and MALDI-TOF results as well as Single-Crystal X-Ray Crystallography for CyR.

AB - Detection of bisulfite (HSO3−) in food and beverages has vital importance because the excessive amount leads to ill effects on the human body. Colorimetric and fluorometric chromenylium-cyanine-based chemosensor CyR was synthesized and applied for high selective and sensitive analysis of HSO3− in red wine, rose wine and, granulated sugar with high recovery ranges and very fast response time without any interference from other competitive species. The limits of detection (LOD) for the UV–Vis and fluorescence titrations were found as 11.5 μM and 3.77 μM, respectively. The on-site and very rapid methods based on paper strips and smartphone which depend on the color changes from yellow to green have been successfully developed to analyze HSO3− concentration (10−5-10−1 M for paper strip and 163–1205 μM for smartphone). CyR and the bisulfite-adduct formed in the nucleophilic addition reaction with HSO3− were verified by FT-IR, 1H NMR, and MALDI-TOF results as well as Single-Crystal X-Ray Crystallography for CyR.

KW - Bisulfite-probe

KW - Chromenylium-cyanine

KW - Colorimetric

KW - Fluorometric

KW - Near-infrared

KW - Smartphone

UR - http://www.scopus.com/inward/record.url?scp=85159197373&partnerID=8YFLogxK

U2 - 10.1016/j.talanta.2023.124660

DO - 10.1016/j.talanta.2023.124660

M3 - Article

C2 - 37207509

AN - SCOPUS:85159197373

SN - 0039-9140

VL - 261

JO - Talanta

JF - Talanta

M1 - 124660

ER -

Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site food and beverages control

Abstract

Bibliographical note

Funding

Keywords

Access to Document

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Press/Media

Istanbul Technical University Reports Findings in Science (Colorimetric and near-infrared spectrophotometric monitoring of bisulfite using glyoxal modified chromenylium-cyanine chemosensor: Smartphone and paper strip applications for on-site ...)

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