Co-ordination of copper and silver by [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6]

Funda Demirhan; Sevil Irişli; Spencer N. Salek; Ozan S. Şentürk; Michael J. Went; John C. Jeffery

doi:10.1016/0022-328X(93)83134-H

Co-ordination of copper and silver by [Co₂{μ-C₂(CH₂SCH₂CH₂)₂S}(CO)₆]

Funda Demirhan^*
, Sevil Irişli
, Spencer N. Salek
, Ozan S. Şentürk
, Michael J. Went
, John C. Jeffery

^*Corresponding author for this work

University Chemicalo laboratory
University of Bristol

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The thiamacrocycle [Co₂{μ-C₂(CH₂SCH₂CH₂)₂S}(CO)₆] reacts with Ag[BF₄] and PPh₃ to afford the fluxional compound [Co₂{μ-C₂(CH₂SCH₂)₂S}(CO)₆(AgPPh₃)][BF₄], the structure of which has been established by X-ray crystallography, and with [Cu(CH_3-CN)₄][PF₆] to afford [Co₂{μ-C₂(CH₂SCH₂CH₂)₂S}(CO)₆(CuCH_3-CN)][PF₆], which undergoes phosphine sustitution.

Original language	English
Pages (from-to)	C30-C31
Journal	Journal of Organometallic Chemistry
Volume	453
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(93)83134-H
Publication status	Published - 13 Jul 1993
Externally published	Yes

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@article{f28bfc04e9244637a39f5ba7932eacc9,

title = "Co-ordination of copper and silver by [Co2\{μ-C2(CH2SCH2CH2)2S\}(CO)6]",

abstract = "The thiamacrocycle [Co2\{μ-C2(CH2SCH2CH2)2S\}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2\{μ-C2(CH2SCH2)2S\}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2\{μ-C2(CH2SCH2CH2)2S\}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine sustitution.",

author = "Funda Demirhan and Sevil Iri{\c s}li and \{N. Salek\}, Spencer and {\c S}ent{\"u}rk, \{Ozan S.\} and Went, \{Michael J.\} and Jeffery, \{John C.\}",

year = "1993",

month = jul,

day = "13",

doi = "10.1016/0022-328X(93)83134-H",

language = "English",

volume = "453",

pages = "C30--C31",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Co-ordination of copper and silver by [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6]

AU - Demirhan, Funda

AU - Irişli, Sevil

AU - N. Salek, Spencer

AU - Şentürk, Ozan S.

AU - Went, Michael J.

AU - Jeffery, John C.

PY - 1993/7/13

Y1 - 1993/7/13

N2 - The thiamacrocycle [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{μ-C2(CH2SCH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine sustitution.

AB - The thiamacrocycle [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{μ-C2(CH2SCH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine sustitution.

UR - https://www.scopus.com/pages/publications/34447564026

U2 - 10.1016/0022-328X(93)83134-H

DO - 10.1016/0022-328X(93)83134-H

M3 - Article

AN - SCOPUS:34447564026

SN - 0022-328X

VL - 453

SP - C30-C31

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Co-ordination of copper and silver by [Co₂{μ-C₂(CH₂SCH₂CH₂)₂S}(CO)₆]

Abstract

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