TY - JOUR
T1 - Chemical polymerization of pyrrole in the presence of ketone-formaldehyde resins
AU - Kizilcan, Nilgün
AU - Ustamehmetoǧlu, Belkis
PY - 2005/5/5
Y1 - 2005/5/5
N2 - The chemical polymerizations of pyrrole in the presence of acetophenone and formaldehyde, cyclohexanone, acetaldehyde, and formaldehyde, cyclohexanone and formaldehyde, cyclohexanone, resorcinol, and formaldehyde, cyclohexanone and lignosulfonate formaldehyde, and cyclohexanone, pyrrole, and formaldehyde were accomplished with Ce(IV) salt in acetonitrile solutions. The roles of the resin type, the addition order of the reactants, and the concentrations of the pyrrole and resin on the solubility and conductivity of the resulting products were investigated. The cyclohexanone-acetaldehyde-formaldehyde resin/ polypyrrole copolymer had the highest solubility in dimethylformamide. The conductivity and solubility of the copolymers could be controlled by the Ce(IV)/pyrrole/resin molar ratio.
AB - The chemical polymerizations of pyrrole in the presence of acetophenone and formaldehyde, cyclohexanone, acetaldehyde, and formaldehyde, cyclohexanone and formaldehyde, cyclohexanone, resorcinol, and formaldehyde, cyclohexanone and lignosulfonate formaldehyde, and cyclohexanone, pyrrole, and formaldehyde were accomplished with Ce(IV) salt in acetonitrile solutions. The roles of the resin type, the addition order of the reactants, and the concentrations of the pyrrole and resin on the solubility and conductivity of the resulting products were investigated. The cyclohexanone-acetaldehyde-formaldehyde resin/ polypyrrole copolymer had the highest solubility in dimethylformamide. The conductivity and solubility of the copolymers could be controlled by the Ce(IV)/pyrrole/resin molar ratio.
KW - Conducting polymers
KW - Copolymerization
KW - Polypyrroles
KW - Redox polymers
KW - Resins
UR - http://www.scopus.com/inward/record.url?scp=17444422883&partnerID=8YFLogxK
U2 - 10.1002/app.21437
DO - 10.1002/app.21437
M3 - Article
AN - SCOPUS:17444422883
SN - 0021-8995
VL - 96
SP - 618
EP - 624
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
IS - 3
ER -