Chemical polymerization of acrylamide initiated with Ce(IV)-dicarboxylic acid redox system: Effect of chain length between the carboxyl groups

B. Ustamehmetoǧlu; Z. I. Diler; A. S. Saraç

doi:10.1080/10236660213160

Chemical polymerization of acrylamide initiated with Ce(IV)-dicarboxylic acid redox system: Effect of chain length between the carboxyl groups

B. Ustamehmetoǧlu^*, Z. I. Diler, A. S. Saraç

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Aqueous polymerization of acrylamide (AAm) was carried out with the Ce(IV)-dicarboxylic acid initiator system. Dicarboxylic acids with numbers of methylene groups ranging from 1 to 7 were used to elucidate the effect of chain length between the carboxyl groups on the formation of polymer, which is reflected in yield and molecular weight of polymer. The end group analysis of polyacrylamides was carried out by using conductometric titration. The number average molecular weight results from end group analysis are compared with values from viscometric analysis.

Original language	English
Pages (from-to)	263-272
Number of pages	10
Journal	International Journal of Polymer Analysis and Characterization
Volume	7
Issue number	4
DOIs	https://doi.org/10.1080/10236660213160
Publication status	Published - 2002

Keywords

Chemical polymerization
Dicarboxylic acid
Polycrylamide

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10.1080/10236660213160

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T1 - Chemical polymerization of acrylamide initiated with Ce(IV)-dicarboxylic acid redox system

T2 - Effect of chain length between the carboxyl groups

AU - Ustamehmetoǧlu, B.

AU - Diler, Z. I.

AU - Saraç, A. S.

PY - 2002

Y1 - 2002

N2 - Aqueous polymerization of acrylamide (AAm) was carried out with the Ce(IV)-dicarboxylic acid initiator system. Dicarboxylic acids with numbers of methylene groups ranging from 1 to 7 were used to elucidate the effect of chain length between the carboxyl groups on the formation of polymer, which is reflected in yield and molecular weight of polymer. The end group analysis of polyacrylamides was carried out by using conductometric titration. The number average molecular weight results from end group analysis are compared with values from viscometric analysis.

AB - Aqueous polymerization of acrylamide (AAm) was carried out with the Ce(IV)-dicarboxylic acid initiator system. Dicarboxylic acids with numbers of methylene groups ranging from 1 to 7 were used to elucidate the effect of chain length between the carboxyl groups on the formation of polymer, which is reflected in yield and molecular weight of polymer. The end group analysis of polyacrylamides was carried out by using conductometric titration. The number average molecular weight results from end group analysis are compared with values from viscometric analysis.

KW - Chemical polymerization

KW - Dicarboxylic acid

KW - Polycrylamide

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JO - International Journal of Polymer Analysis and Characterization

JF - International Journal of Polymer Analysis and Characterization

IS - 4

ER -

Chemical polymerization of acrylamide initiated with Ce(IV)-dicarboxylic acid redox system: Effect of chain length between the carboxyl groups

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Keywords

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