Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers

Türkan Doǧan; Nilgün Baydoǧan; Nesrin Köken

doi:10.1063/1.4944196

Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers

Türkan Doǧan
, Nilgün Baydoǧan
, Nesrin Köken

Istanbul Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

4 Citations (Scopus)

Abstract

Poly(imide siloxane) block copolymers with the same polydimethlysiloxane(APPS) were prepared by using 4,4'-oxydianiline (ODA) and Benzofenon-3,3,4,4-tetrakarboksilik dianhydride(BTDA) to compose the polyimide hard block. APPS and BTDA composed the polysiloxane soft block. The length of polysiloxane soft blocks increased with increasing the length of polyimide hard block. Copolymerization of soft and hard segments were determined by using this method. Copolymer structures could be obtained by holding constant hard block segments and by adjusting and increasing soft block segments. Thus, more flexible randomly segmented poly(imide siloxane) block copolymers can be obtained. These composed structure as flexible and high performance copolymers were characterized by FT-IR and evaluated. The structures were tested mechanically to detect their elastic recovery property as flexible material. The characterization of the samples enabled to examine flexible substrates in order to use in solar cell, aerospace applications and microelectronic devices.

Original language	English
Title of host publication	9th International Physics Conference of the Balkan Physical Union, BPU 2015
Editors	Baki Akkus, Gulfem Susoy Dogan, R. Burcu Cakirli Mutlu, Latife Sahin Yalcin, Yesim Oktem
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735413696
DOIs	https://doi.org/10.1063/1.4944196
Publication status	Published - 25 Mar 2016
Event	9th International Physics Conference of the Balkan Physical Union, BPU 2015 - Istanbul, Turkey Duration: 24 Aug 2015 → 27 Aug 2015

Publication series

Name	AIP Conference Proceedings
Volume	1722
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	9th International Physics Conference of the Balkan Physical Union, BPU 2015
Country/Territory	Turkey
City	Istanbul
Period	24/08/15 → 27/08/15

Bibliographical note

Publisher Copyright:
© 2016 AIP Publishing LLC.

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10.1063/1.4944196

Cite this

Doǧan, T., Baydoǧan, N., & Köken, N. (2016). Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers. In B. Akkus, G. S. Dogan, R. B. C. Mutlu, L. S. Yalcin, & Y. Oktem (Eds.), 9th International Physics Conference of the Balkan Physical Union, BPU 2015 Article 140006 (AIP Conference Proceedings; Vol. 1722). American Institute of Physics Inc.. https://doi.org/10.1063/1.4944196

Doǧan, Türkan ; Baydoǧan, Nilgün ; Köken, Nesrin. / Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers. 9th International Physics Conference of the Balkan Physical Union, BPU 2015. editor / Baki Akkus ; Gulfem Susoy Dogan ; R. Burcu Cakirli Mutlu ; Latife Sahin Yalcin ; Yesim Oktem. American Institute of Physics Inc., 2016. (AIP Conference Proceedings).

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title = "Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers",

abstract = "Poly(imide siloxane) block copolymers with the same polydimethlysiloxane(APPS) were prepared by using 4,4'-oxydianiline (ODA) and Benzofenon-3,3,4,4-tetrakarboksilik dianhydride(BTDA) to compose the polyimide hard block. APPS and BTDA composed the polysiloxane soft block. The length of polysiloxane soft blocks increased with increasing the length of polyimide hard block. Copolymerization of soft and hard segments were determined by using this method. Copolymer structures could be obtained by holding constant hard block segments and by adjusting and increasing soft block segments. Thus, more flexible randomly segmented poly(imide siloxane) block copolymers can be obtained. These composed structure as flexible and high performance copolymers were characterized by FT-IR and evaluated. The structures were tested mechanically to detect their elastic recovery property as flexible material. The characterization of the samples enabled to examine flexible substrates in order to use in solar cell, aerospace applications and microelectronic devices.",

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Doǧan, T, Baydoǧan, N & Köken, N 2016, Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers. in B Akkus, GS Dogan, RBC Mutlu, LS Yalcin & Y Oktem (eds), 9th International Physics Conference of the Balkan Physical Union, BPU 2015., 140006, AIP Conference Proceedings, vol. 1722, American Institute of Physics Inc., 9th International Physics Conference of the Balkan Physical Union, BPU 2015, Istanbul, Turkey, 24/08/15. https://doi.org/10.1063/1.4944196

Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers. / Doǧan, Türkan; Baydoǧan, Nilgün ; Köken, Nesrin.
9th International Physics Conference of the Balkan Physical Union, BPU 2015. ed. / Baki Akkus; Gulfem Susoy Dogan; R. Burcu Cakirli Mutlu; Latife Sahin Yalcin; Yesim Oktem. American Institute of Physics Inc., 2016. 140006 (AIP Conference Proceedings; Vol. 1722).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers

AU - Doǧan, Türkan

AU - Baydoǧan, Nilgün

AU - Köken, Nesrin

PY - 2016/3/25

Y1 - 2016/3/25

N2 - Poly(imide siloxane) block copolymers with the same polydimethlysiloxane(APPS) were prepared by using 4,4'-oxydianiline (ODA) and Benzofenon-3,3,4,4-tetrakarboksilik dianhydride(BTDA) to compose the polyimide hard block. APPS and BTDA composed the polysiloxane soft block. The length of polysiloxane soft blocks increased with increasing the length of polyimide hard block. Copolymerization of soft and hard segments were determined by using this method. Copolymer structures could be obtained by holding constant hard block segments and by adjusting and increasing soft block segments. Thus, more flexible randomly segmented poly(imide siloxane) block copolymers can be obtained. These composed structure as flexible and high performance copolymers were characterized by FT-IR and evaluated. The structures were tested mechanically to detect their elastic recovery property as flexible material. The characterization of the samples enabled to examine flexible substrates in order to use in solar cell, aerospace applications and microelectronic devices.

AB - Poly(imide siloxane) block copolymers with the same polydimethlysiloxane(APPS) were prepared by using 4,4'-oxydianiline (ODA) and Benzofenon-3,3,4,4-tetrakarboksilik dianhydride(BTDA) to compose the polyimide hard block. APPS and BTDA composed the polysiloxane soft block. The length of polysiloxane soft blocks increased with increasing the length of polyimide hard block. Copolymerization of soft and hard segments were determined by using this method. Copolymer structures could be obtained by holding constant hard block segments and by adjusting and increasing soft block segments. Thus, more flexible randomly segmented poly(imide siloxane) block copolymers can be obtained. These composed structure as flexible and high performance copolymers were characterized by FT-IR and evaluated. The structures were tested mechanically to detect their elastic recovery property as flexible material. The characterization of the samples enabled to examine flexible substrates in order to use in solar cell, aerospace applications and microelectronic devices.

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T3 - AIP Conference Proceedings

BT - 9th International Physics Conference of the Balkan Physical Union, BPU 2015

A2 - Akkus, Baki

A2 - Dogan, Gulfem Susoy

A2 - Mutlu, R. Burcu Cakirli

A2 - Yalcin, Latife Sahin

A2 - Oktem, Yesim

PB - American Institute of Physics Inc.

T2 - 9th International Physics Conference of the Balkan Physical Union, BPU 2015

Y2 - 24 August 2015 through 27 August 2015

ER -

Doǧan T, Baydoǧan N , Köken N. Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers. In Akkus B, Dogan GS, Mutlu RBC, Yalcin LS, Oktem Y, editors, 9th International Physics Conference of the Balkan Physical Union, BPU 2015. American Institute of Physics Inc. 2016. 140006. (AIP Conference Proceedings). doi: 10.1063/1.4944196

Characterization of high performance randomly segmented poly(urethane siloxane) and poly(imide siloxane) block copolymers

Abstract

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Bibliographical note

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