Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether

Kerem Kaya; Tapas Debsharma; Helmut Schlaad; Yusuf Yagci

doi:10.1039/d0py01307b

Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether

Kerem Kaya, Tapas Debsharma, Helmut Schlaad^*, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

This study aims to explore the photoinitiated cationic ring-opening polymerization of levoglucosenyl methyl ether (LGME), a chemical obtained from the most abundant biomass-cellulose. Direct and sensitized photopolymerizations of LGME using photoinitiators acting at the near UV or visible range in conjunction with diphenyliodonium hexafluoroantimonate (DPI) yielded unsaturated polyacetals with varying molar masses and distributions.

Original language	English
Pages (from-to)	6884-6889
Number of pages	6
Journal	Polymer Chemistry
Volume	11
Issue number	43
DOIs	https://doi.org/10.1039/d0py01307b
Publication status	Published - 21 Nov 2020

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry.

Access to Document

10.1039/d0py01307b

Cite this

@article{460f6634dacf46edbad92add681cfdc9,

title = "Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether",

abstract = "This study aims to explore the photoinitiated cationic ring-opening polymerization of levoglucosenyl methyl ether (LGME), a chemical obtained from the most abundant biomass-cellulose. Direct and sensitized photopolymerizations of LGME using photoinitiators acting at the near UV or visible range in conjunction with diphenyliodonium hexafluoroantimonate (DPI) yielded unsaturated polyacetals with varying molar masses and distributions.",

author = "Kerem Kaya and Tapas Debsharma and Helmut Schlaad and Yusuf Yagci",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = nov,

day = "21",

doi = "10.1039/d0py01307b",

language = "English",

volume = "11",

pages = "6884--6889",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether

AU - Kaya, Kerem

AU - Debsharma, Tapas

AU - Schlaad, Helmut

AU - Yagci, Yusuf

PY - 2020/11/21

Y1 - 2020/11/21

N2 - This study aims to explore the photoinitiated cationic ring-opening polymerization of levoglucosenyl methyl ether (LGME), a chemical obtained from the most abundant biomass-cellulose. Direct and sensitized photopolymerizations of LGME using photoinitiators acting at the near UV or visible range in conjunction with diphenyliodonium hexafluoroantimonate (DPI) yielded unsaturated polyacetals with varying molar masses and distributions.

AB - This study aims to explore the photoinitiated cationic ring-opening polymerization of levoglucosenyl methyl ether (LGME), a chemical obtained from the most abundant biomass-cellulose. Direct and sensitized photopolymerizations of LGME using photoinitiators acting at the near UV or visible range in conjunction with diphenyliodonium hexafluoroantimonate (DPI) yielded unsaturated polyacetals with varying molar masses and distributions.

UR - http://www.scopus.com/inward/record.url?scp=85096361552&partnerID=8YFLogxK

U2 - 10.1039/d0py01307b

DO - 10.1039/d0py01307b

M3 - Article

AN - SCOPUS:85096361552

SN - 1759-9954

VL - 11

SP - 6884

EP - 6889

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 43

ER -

Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this