Cationic polymerization of cyclohexene oxide initiated by a ternary system consisting of free radical photoinitiator, diphenyl acetylene and triphenylsulphonium salt

Ash Okan; I. Ersin Serhatli; Yusuf Yağci

doi:10.1007/BF00295769

Cationic polymerization of cyclohexene oxide initiated by a ternary system consisting of free radical photoinitiator, diphenyl acetylene and triphenylsulphonium salt

Ash Okan, I. Ersin Serhatli, Yusuf Yağci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Vinyl cation-based initiating system for cationic polymerization of cyclohexene oxide (CHO) has been developed by using photochemical free radical sources in conjuction with diphenyl acetylene (DPA) and triphenyl sulphonium hexafluorophosphate. An initiation mechanism involving the formation of substituted vinyl radical and subsequent oxidation to the corresponding cations is proposed.

Original language	English
Pages (from-to)	723-728
Number of pages	6
Journal	Polymer Bulletin
Volume	37
Issue number	6
DOIs	https://doi.org/10.1007/BF00295769
Publication status	Published - Dec 1996

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title = "Cationic polymerization of cyclohexene oxide initiated by a ternary system consisting of free radical photoinitiator, diphenyl acetylene and triphenylsulphonium salt",

abstract = "Vinyl cation-based initiating system for cationic polymerization of cyclohexene oxide (CHO) has been developed by using photochemical free radical sources in conjuction with diphenyl acetylene (DPA) and triphenyl sulphonium hexafluorophosphate. An initiation mechanism involving the formation of substituted vinyl radical and subsequent oxidation to the corresponding cations is proposed.",

author = "Ash Okan and Serhatli, {I. Ersin} and Yusuf Yağci",

year = "1996",

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T1 - Cationic polymerization of cyclohexene oxide initiated by a ternary system consisting of free radical photoinitiator, diphenyl acetylene and triphenylsulphonium salt

AU - Okan, Ash

AU - Serhatli, I. Ersin

AU - Yağci, Yusuf

PY - 1996/12

Y1 - 1996/12

N2 - Vinyl cation-based initiating system for cationic polymerization of cyclohexene oxide (CHO) has been developed by using photochemical free radical sources in conjuction with diphenyl acetylene (DPA) and triphenyl sulphonium hexafluorophosphate. An initiation mechanism involving the formation of substituted vinyl radical and subsequent oxidation to the corresponding cations is proposed.

AB - Vinyl cation-based initiating system for cationic polymerization of cyclohexene oxide (CHO) has been developed by using photochemical free radical sources in conjuction with diphenyl acetylene (DPA) and triphenyl sulphonium hexafluorophosphate. An initiation mechanism involving the formation of substituted vinyl radical and subsequent oxidation to the corresponding cations is proposed.

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U2 - 10.1007/BF00295769

DO - 10.1007/BF00295769

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SN - 0170-0839

VL - 37

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JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 6

ER -

Cationic polymerization of cyclohexene oxide initiated by a ternary system consisting of free radical photoinitiator, diphenyl acetylene and triphenylsulphonium salt

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