Abstract
Two new compounds, BODIPY-tetraphenylethylene dyad and BODIPY-o-carborane-tetraphenylethylene triad, were designed and synthesized. This molecular dyad and triad have been characterized by using various spectroscopic methods, including FT-IR, mass, UV-visible absorption and fluorescence emission spectroscopy, and one and two-dimensional homo- and hetero-correlated NMR spectroscopy. Photophysical properties, as well as solvatochromic and aggregation-induced emission (AIE) behavior, have been investigated. Single-crystal X-ray diffraction analysis has unambiguously revealed their structure and provides an explanation for the absence of AIE character. The redox properties showed that an o-carborane addition increased the reduction potential and shifted the oxidation potential to the positive site.
| Original language | English |
|---|---|
| Pages (from-to) | 4471-4476 |
| Number of pages | 6 |
| Journal | New Journal of Chemistry |
| Volume | 43 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2019 |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
Funding
This study was supported by the Research Fund of Istanbul Technical University.
| Funders |
|---|
| Istanbul Teknik Üniversitesi |
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