Block copolymer synthesis by atom transfer radical polymerization

Knysuof Matyjaszewski, Metin H. Acar, Kathryn L. Beers, Simian Coca, Kelly A. Davis, Scott G. Gaynor, Peter J. Miller, Hyun Jong Paik, Devon A. Shipp, Mircea Teodorescu, Jianhui Xia, Xuan Zhang

Research output: Contribution to journalConference articlepeer-review

13 Citations (Scopus)

Abstract

Atom transfer radical polymerization (ATRP) provides a simple, useful and effective route for the synthesis of many block copolymers. The utility of ATRP lies in the method's ability to polymerize many monomers under non-strenuous conditions and the functionality introduced to the polymer through the halide end groups. This functionality allows the polymer chains to be extended by further ATRP. Furthermore, cross-propagation can be improved through halide exchange, this ability is unique to ATRP when compared with other controlled/living radical polymerizations. Other polymerization mechanisms can also be used in conjunction with ATRP after suitable end group transformation reactions.

Original languageEnglish
Pages (from-to)966-967
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume40
Issue number2
Publication statusPublished - Aug 1999
Externally publishedYes

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