Abstract
Atom transfer radical polymerization (ATRP) provides a simple, useful and effective route for the synthesis of many block copolymers. The utility of ATRP lies in the method's ability to polymerize many monomers under non-strenuous conditions and the functionality introduced to the polymer through the halide end groups. This functionality allows the polymer chains to be extended by further ATRP. Furthermore, cross-propagation can be improved through halide exchange, this ability is unique to ATRP when compared with other controlled/living radical polymerizations. Other polymerization mechanisms can also be used in conjunction with ATRP after suitable end group transformation reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 966-967 |
| Number of pages | 2 |
| Journal | American Chemical Society, Polymer Preprints, Division of Polymer Chemistry |
| Volume | 40 |
| Issue number | 2 |
| Publication status | Published - Aug 1999 |
| Externally published | Yes |