TY - JOUR
T1 - Bifunctional initiators
T2 - Synthesis, characterization, and initiator properties of azo-benzoin initiators
AU - Önen, Aysen
AU - Yaǧci, Yusuf
PY - 1990
Y1 - 1990
N2 - Two new azo-benzoin initiators were synthesized by the condensation of 4,4′-azo-bis-(4-cyanopentanoic acid chloride) (ACPC) with benzoin (B) and α-methylolbenzoin methyl ether. The initiator structures were confirmed by IR and NMR spectroscopy. The kinetics of the bulk polymerization of styrene initiated by the azo-benzoin initiator, obtained from ACPC and B, was investigated and the kinetic parameters evaluated. The initiation of polymerization of styrene by means of azo-benzoin initiators yields polymers with terminal photoactive benzoin groups.
AB - Two new azo-benzoin initiators were synthesized by the condensation of 4,4′-azo-bis-(4-cyanopentanoic acid chloride) (ACPC) with benzoin (B) and α-methylolbenzoin methyl ether. The initiator structures were confirmed by IR and NMR spectroscopy. The kinetics of the bulk polymerization of styrene initiated by the azo-benzoin initiator, obtained from ACPC and B, was investigated and the kinetic parameters evaluated. The initiation of polymerization of styrene by means of azo-benzoin initiators yields polymers with terminal photoactive benzoin groups.
UR - http://www.scopus.com/inward/record.url?scp=0025444527&partnerID=8YFLogxK
U2 - 10.1080/00222339009349655
DO - 10.1080/00222339009349655
M3 - Article
AN - SCOPUS:0025444527
SN - 0022-233X
VL - 27
SP - 743
EP - 753
JO - Journal of Macromolecular Science - Pure and Applied Chemistry
JF - Journal of Macromolecular Science - Pure and Applied Chemistry
IS - 6
ER -