Benzylation of alcohols by using bis[acetylacetonato]copper as catalyst

Okan Sirkecioglu; Bekir Karliga; Naciye Talinli

doi:10.1016/j.tetlet.2003.09.106

Benzylation of alcohols by using bis[acetylacetonato]copper as catalyst

Okan Sirkecioglu^*, Bekir Karliga, Naciye Talinli

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Selective O-benzylation of primary hydroxy compounds has been achieved in the presence of bis[acetylacetonato]copper with benzyl chloride. We showed that bis[acetylacetonato]copper was very efficient in promoting the benzylation of primary aliphatic alcohols versus secondary aliphatic alcohols and phenolic hydroxy groups selectively.

Original language	English
Pages (from-to)	8483-8485
Number of pages	3
Journal	Tetrahedron Letters
Volume	44
Issue number	46
DOIs	https://doi.org/10.1016/j.tetlet.2003.09.106
Publication status	Published - 10 Nov 2003

Keywords

Benzylic ether
Bis[acetylacetonato]copper
Selective etherification

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10.1016/j.tetlet.2003.09.106

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title = "Benzylation of alcohols by using bis[acetylacetonato]copper as catalyst",

abstract = "Selective O-benzylation of primary hydroxy compounds has been achieved in the presence of bis[acetylacetonato]copper with benzyl chloride. We showed that bis[acetylacetonato]copper was very efficient in promoting the benzylation of primary aliphatic alcohols versus secondary aliphatic alcohols and phenolic hydroxy groups selectively.",

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author = "Okan Sirkecioglu and Bekir Karliga and Naciye Talinli",

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T1 - Benzylation of alcohols by using bis[acetylacetonato]copper as catalyst

AU - Sirkecioglu, Okan

AU - Karliga, Bekir

AU - Talinli, Naciye

PY - 2003/11/10

Y1 - 2003/11/10

N2 - Selective O-benzylation of primary hydroxy compounds has been achieved in the presence of bis[acetylacetonato]copper with benzyl chloride. We showed that bis[acetylacetonato]copper was very efficient in promoting the benzylation of primary aliphatic alcohols versus secondary aliphatic alcohols and phenolic hydroxy groups selectively.

AB - Selective O-benzylation of primary hydroxy compounds has been achieved in the presence of bis[acetylacetonato]copper with benzyl chloride. We showed that bis[acetylacetonato]copper was very efficient in promoting the benzylation of primary aliphatic alcohols versus secondary aliphatic alcohols and phenolic hydroxy groups selectively.

KW - Benzylic ether

KW - Bis[acetylacetonato]copper

KW - Selective etherification

UR - https://www.scopus.com/pages/publications/0141887555

U2 - 10.1016/j.tetlet.2003.09.106

DO - 10.1016/j.tetlet.2003.09.106

M3 - Article

AN - SCOPUS:0141887555

SN - 0040-4039

VL - 44

SP - 8483

EP - 8485

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

Benzylation of alcohols by using bis[acetylacetonato]copper as catalyst

Abstract

Keywords

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