Analysis of anthraquinones in Rumex crispus by micellar electrokinetic chromatography

Selda Başkan; Ayşe Daut-Özdemir; Keriman Günaydin; F. Bedia Erim

doi:10.1016/j.talanta.2006.05.018

Analysis of anthraquinones in Rumex crispus by micellar electrokinetic chromatography

Selda Başkan
, Ayşe Daut-Özdemir
, Keriman Günaydin
, F. Bedia Erim^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University
Istanbul University

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

A micellar electrochromatographic method was performed for the analysis of the pharmaceutically important anthraquinones from the root of Rumex crispus. The separation of 1,5-dihydroxy-3-methylanthraquinone (1); 1,3,5-trihydroxy-6-hydroxymethylanthraquinone (2); 1,5-dihydroxy-3-methoxy-7-methylanthraquinone (3) was achieved in 6 min using a running buffer containing 10 mmol/l sodium borate, 50 mmol/l sodium dodecylsulfate, and 25% acetonitrile at pH 10.6. The method is simple, rapid, and reproducible.

Original language	English
Pages (from-to)	747-750
Number of pages	4
Journal	Talanta
Volume	71
Issue number	2
DOIs	https://doi.org/10.1016/j.talanta.2006.05.018
Publication status	Published - 15 Feb 2007

Funding

We thank the TÜBITAK (Grant TBA6-2312, 103T053) for financial support.

Funders	Funder number
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	103T053, TBA6-2312

Keywords

Anthraquinones
Capillary electrophoresis
MEKC
Rumex crispus

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10.1016/j.talanta.2006.05.018

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title = "Analysis of anthraquinones in Rumex crispus by micellar electrokinetic chromatography",

abstract = "A micellar electrochromatographic method was performed for the analysis of the pharmaceutically important anthraquinones from the root of Rumex crispus. The separation of 1,5-dihydroxy-3-methylanthraquinone (1); 1,3,5-trihydroxy-6-hydroxymethylanthraquinone (2); 1,5-dihydroxy-3-methoxy-7-methylanthraquinone (3) was achieved in 6 min using a running buffer containing 10 mmol/l sodium borate, 50 mmol/l sodium dodecylsulfate, and 25\% acetonitrile at pH 10.6. The method is simple, rapid, and reproducible.",

keywords = "Anthraquinones, Capillary electrophoresis, MEKC, Rumex crispus",

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doi = "10.1016/j.talanta.2006.05.018",

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AU - Başkan, Selda

AU - Daut-Özdemir, Ayşe

AU - Günaydin, Keriman

AU - Erim, F. Bedia

PY - 2007/2/15

Y1 - 2007/2/15

N2 - A micellar electrochromatographic method was performed for the analysis of the pharmaceutically important anthraquinones from the root of Rumex crispus. The separation of 1,5-dihydroxy-3-methylanthraquinone (1); 1,3,5-trihydroxy-6-hydroxymethylanthraquinone (2); 1,5-dihydroxy-3-methoxy-7-methylanthraquinone (3) was achieved in 6 min using a running buffer containing 10 mmol/l sodium borate, 50 mmol/l sodium dodecylsulfate, and 25% acetonitrile at pH 10.6. The method is simple, rapid, and reproducible.

AB - A micellar electrochromatographic method was performed for the analysis of the pharmaceutically important anthraquinones from the root of Rumex crispus. The separation of 1,5-dihydroxy-3-methylanthraquinone (1); 1,3,5-trihydroxy-6-hydroxymethylanthraquinone (2); 1,5-dihydroxy-3-methoxy-7-methylanthraquinone (3) was achieved in 6 min using a running buffer containing 10 mmol/l sodium borate, 50 mmol/l sodium dodecylsulfate, and 25% acetonitrile at pH 10.6. The method is simple, rapid, and reproducible.

KW - Anthraquinones

KW - Capillary electrophoresis

KW - MEKC

KW - Rumex crispus

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DO - 10.1016/j.talanta.2006.05.018

M3 - Article

AN - SCOPUS:33846211484

SN - 0039-9140

VL - 71

SP - 747

EP - 750

JO - Talanta

JF - Talanta

IS - 2

ER -

Analysis of anthraquinones in Rumex crispus by micellar electrokinetic chromatography

Abstract

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