An investigation on the self-propagating high temperature synthesis of TiB2

Onuralp Yucel; Mehmet Bugdayci; Ahmet Turan

doi:10.1002/9781118887998.ch19

An investigation on the self-propagating high temperature synthesis of TiB₂

Onuralp Yucel, Mehmet Bugdayci, Ahmet Turan

Department of Metallurgical and Materials Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

TiB₂ is a transition metal boride which has remarkable properties such as high melting temperature, hardness, thermal and electrical conductivity, good wear, thermal shock and corrosion resistance. Self-propagating high temperature synthesis (SHS) followed by acid leaching was applied in this study to synthesize TiB₂ powders with ultra-fine grain size and high energy efficiency. Investigated parameters were Mg stoichiometry as 90%, 100% and 110%, process atmosphere as air and argon atmosphere and effect of MgSO₄ and NaCl as catalyst on the quality and grain size of synthesized TiB2 powders. SHS reactions were carried out in a cylindrical copper crucible. SHS products were leached by using concentrated HC1 solutions. Leaching parameters were 9.25 molar HC1 concentration, 600 rpm stirring speed and 1/5 solid/liquid ratio. X-Ray Diffraction (XRD), BET specific surface area measurement and chemical analysis techniques were performed for the characterization of SHS and leaching products.

Original language	English
Title of host publication	5th International Symposium on High-Temperature Metallurgical Processing - Held During TMS 2014 143rd Annual Meeting and Exhibition
Publisher	Minerals, Metals and Materials Society
Pages	147-151
Number of pages	5
ISBN (Print)	9781118888117
DOIs	https://doi.org/10.1002/9781118887998.ch19
Publication status	Published - 2014
Event	5th International Symposium on High-Temperature Metallurgical Processing - TMS 2014 143rd Annual Meeting and Exhibition - San Diego, CA, United States Duration: 16 Feb 2014 → 20 Feb 2014

Publication series

Name	TMS Annual Meeting

Conference

Conference	5th International Symposium on High-Temperature Metallurgical Processing - TMS 2014 143rd Annual Meeting and Exhibition
Country/Territory	United States
City	San Diego, CA
Period	16/02/14 → 20/02/14

Keywords

Self-propagating high temperature synthesis
Titanium diboride

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/9781118887998.ch19

Cite this

Yucel, O., Bugdayci, M., & Turan, A. (2014). An investigation on the self-propagating high temperature synthesis of TiB₂. In 5th International Symposium on High-Temperature Metallurgical Processing - Held During TMS 2014 143rd Annual Meeting and Exhibition (pp. 147-151). (TMS Annual Meeting). Minerals, Metals and Materials Society. https://doi.org/10.1002/9781118887998.ch19

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title = "An investigation on the self-propagating high temperature synthesis of TiB2",

abstract = "TiB2 is a transition metal boride which has remarkable properties such as high melting temperature, hardness, thermal and electrical conductivity, good wear, thermal shock and corrosion resistance. Self-propagating high temperature synthesis (SHS) followed by acid leaching was applied in this study to synthesize TiB2 powders with ultra-fine grain size and high energy efficiency. Investigated parameters were Mg stoichiometry as 90%, 100% and 110%, process atmosphere as air and argon atmosphere and effect of MgSO4 and NaCl as catalyst on the quality and grain size of synthesized TiB2 powders. SHS reactions were carried out in a cylindrical copper crucible. SHS products were leached by using concentrated HC1 solutions. Leaching parameters were 9.25 molar HC1 concentration, 600 rpm stirring speed and 1/5 solid/liquid ratio. X-Ray Diffraction (XRD), BET specific surface area measurement and chemical analysis techniques were performed for the characterization of SHS and leaching products.",

keywords = "Self-propagating high temperature synthesis, Titanium diboride",

author = "Onuralp Yucel and Mehmet Bugdayci and Ahmet Turan",

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Yucel, O, Bugdayci, M & Turan, A 2014, An investigation on the self-propagating high temperature synthesis of TiB₂. in 5th International Symposium on High-Temperature Metallurgical Processing - Held During TMS 2014 143rd Annual Meeting and Exhibition. TMS Annual Meeting, Minerals, Metals and Materials Society, pp. 147-151, 5th International Symposium on High-Temperature Metallurgical Processing - TMS 2014 143rd Annual Meeting and Exhibition, San Diego, CA, United States, 16/02/14. https://doi.org/10.1002/9781118887998.ch19

An investigation on the self-propagating high temperature synthesis of TiB₂. / Yucel, Onuralp; Bugdayci, Mehmet; Turan, Ahmet.
5th International Symposium on High-Temperature Metallurgical Processing - Held During TMS 2014 143rd Annual Meeting and Exhibition. Minerals, Metals and Materials Society, 2014. p. 147-151 (TMS Annual Meeting).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - An investigation on the self-propagating high temperature synthesis of TiB2

AU - Yucel, Onuralp

AU - Bugdayci, Mehmet

AU - Turan, Ahmet

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N2 - TiB2 is a transition metal boride which has remarkable properties such as high melting temperature, hardness, thermal and electrical conductivity, good wear, thermal shock and corrosion resistance. Self-propagating high temperature synthesis (SHS) followed by acid leaching was applied in this study to synthesize TiB2 powders with ultra-fine grain size and high energy efficiency. Investigated parameters were Mg stoichiometry as 90%, 100% and 110%, process atmosphere as air and argon atmosphere and effect of MgSO4 and NaCl as catalyst on the quality and grain size of synthesized TiB2 powders. SHS reactions were carried out in a cylindrical copper crucible. SHS products were leached by using concentrated HC1 solutions. Leaching parameters were 9.25 molar HC1 concentration, 600 rpm stirring speed and 1/5 solid/liquid ratio. X-Ray Diffraction (XRD), BET specific surface area measurement and chemical analysis techniques were performed for the characterization of SHS and leaching products.

AB - TiB2 is a transition metal boride which has remarkable properties such as high melting temperature, hardness, thermal and electrical conductivity, good wear, thermal shock and corrosion resistance. Self-propagating high temperature synthesis (SHS) followed by acid leaching was applied in this study to synthesize TiB2 powders with ultra-fine grain size and high energy efficiency. Investigated parameters were Mg stoichiometry as 90%, 100% and 110%, process atmosphere as air and argon atmosphere and effect of MgSO4 and NaCl as catalyst on the quality and grain size of synthesized TiB2 powders. SHS reactions were carried out in a cylindrical copper crucible. SHS products were leached by using concentrated HC1 solutions. Leaching parameters were 9.25 molar HC1 concentration, 600 rpm stirring speed and 1/5 solid/liquid ratio. X-Ray Diffraction (XRD), BET specific surface area measurement and chemical analysis techniques were performed for the characterization of SHS and leaching products.

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