An investigation on the adsorption characteristics and orientations model of pyrrole on smooth platinum electrode

I. Becerik; F. Kadirgan

doi:10.1016/0013-4686(96)00161-2

An investigation on the adsorption characteristics and orientations model of pyrrole on smooth platinum electrode

I. Becerik, F. Kadirgan^*

^*Corresponding author for this work

Department of Chemistry

Scientific and Technological Research Council of Turkey

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Since the electropolymerization mechanism is believed to involve the initial adsorption of the monomer on to the electrode surface, in this paper, different criteria for the electroadsorption of pyrrole on a smooth polycrytalline platinum electrode were investigated in different pH media. Experiments were performed in a neutral medium (0.1 M Na₂HPO₄+ 0.1 M KH₂PO₄) and an H₂SO₄ aqueous medium as functions of pyrrole concentration, adsorption time and adsorption potential. The adsorption kinetics and isotherms were studied at constant potential. The number of electrons per occupied site (n_e) and surface coverage ratios (θ) were calculated. Possible orientation models were proposed for adsorbed species.

Original language	English
Pages (from-to)	283-289
Number of pages	7
Journal	Electrochimica Acta
Volume	42
Issue number	2
DOIs	https://doi.org/10.1016/0013-4686(96)00161-2
Publication status	Published - 1997

Keywords

Cyclic voltammetry
Electroadsorption
Pyrrole

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10.1016/0013-4686(96)00161-2

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abstract = "Since the electropolymerization mechanism is believed to involve the initial adsorption of the monomer on to the electrode surface, in this paper, different criteria for the electroadsorption of pyrrole on a smooth polycrytalline platinum electrode were investigated in different pH media. Experiments were performed in a neutral medium (0.1 M Na2HPO4+ 0.1 M KH2PO4) and an H2SO4 aqueous medium as functions of pyrrole concentration, adsorption time and adsorption potential. The adsorption kinetics and isotherms were studied at constant potential. The number of electrons per occupied site (ne) and surface coverage ratios (θ) were calculated. Possible orientation models were proposed for adsorbed species.",

keywords = "Cyclic voltammetry, Electroadsorption, Pyrrole",

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T1 - An investigation on the adsorption characteristics and orientations model of pyrrole on smooth platinum electrode

AU - Becerik, I.

AU - Kadirgan, F.

PY - 1997

Y1 - 1997

N2 - Since the electropolymerization mechanism is believed to involve the initial adsorption of the monomer on to the electrode surface, in this paper, different criteria for the electroadsorption of pyrrole on a smooth polycrytalline platinum electrode were investigated in different pH media. Experiments were performed in a neutral medium (0.1 M Na2HPO4+ 0.1 M KH2PO4) and an H2SO4 aqueous medium as functions of pyrrole concentration, adsorption time and adsorption potential. The adsorption kinetics and isotherms were studied at constant potential. The number of electrons per occupied site (ne) and surface coverage ratios (θ) were calculated. Possible orientation models were proposed for adsorbed species.

AB - Since the electropolymerization mechanism is believed to involve the initial adsorption of the monomer on to the electrode surface, in this paper, different criteria for the electroadsorption of pyrrole on a smooth polycrytalline platinum electrode were investigated in different pH media. Experiments were performed in a neutral medium (0.1 M Na2HPO4+ 0.1 M KH2PO4) and an H2SO4 aqueous medium as functions of pyrrole concentration, adsorption time and adsorption potential. The adsorption kinetics and isotherms were studied at constant potential. The number of electrons per occupied site (ne) and surface coverage ratios (θ) were calculated. Possible orientation models were proposed for adsorbed species.

KW - Cyclic voltammetry

KW - Electroadsorption

KW - Pyrrole

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DO - 10.1016/0013-4686(96)00161-2

M3 - Article

AN - SCOPUS:0030837878

SN - 0013-4686

VL - 42

SP - 283

EP - 289

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 2

ER -

An investigation on the adsorption characteristics and orientations model of pyrrole on smooth platinum electrode

Abstract

Keywords

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