Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution

Fadhil Abid Elaiwi; Ahmet Sirkecioglu

doi:10.1080/01496395.2019.1706571

Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution

Fadhil Abid Elaiwi^*, Ahmet Sirkecioglu

^*Corresponding author for this work

Department of Chemical Engineering

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for single ion and binary ion solutions, respectively. Data revealed that ED-MIL-101(Cr) possess maximum adsorption capacities (mg/g) of 69.9 and 63.15 for Cu(II) and Cd(II), respectively,with affinity order Cu(II) ˃ Cd(II) in binary ion solution. The kinetic data was well described by the pseudo-second-order model. The amino-functionalized MIL-101(Cr) can be a promising candidate for metal ion removal from the aqueous environment.

Original language	English
Pages (from-to)	3362-3374
Number of pages	13
Journal	Separation Science and Technology
Volume	55
Issue number	18
DOIs	https://doi.org/10.1080/01496395.2019.1706571
Publication status	Published - 11 Dec 2020

Bibliographical note

Publisher Copyright:
© 2019 Taylor & Francis Group, LLC.

Keywords

Adsorption
Amine functionalized MIL-101(Cr)
Cadmium
Copper

Access to Document

10.1080/01496395.2019.1706571

Cite this

@article{3eff91d4616e4e5abaf03362c496b44d,

title = "Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution",

abstract = "In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for single ion and binary ion solutions, respectively. Data revealed that ED-MIL-101(Cr) possess maximum adsorption capacities (mg/g) of 69.9 and 63.15 for Cu(II) and Cd(II), respectively,with affinity order Cu(II) ˃ Cd(II) in binary ion solution. The kinetic data was well described by the pseudo-second-order model. The amino-functionalized MIL-101(Cr) can be a promising candidate for metal ion removal from the aqueous environment.",

keywords = "Adsorption, Amine functionalized MIL-101(Cr), Cadmium, Copper",

author = "Elaiwi, {Fadhil Abid} and Ahmet Sirkecioglu",

note = "Publisher Copyright: {\textcopyright} 2019 Taylor & Francis Group, LLC.",

year = "2020",

month = dec,

day = "11",

doi = "10.1080/01496395.2019.1706571",

language = "English",

volume = "55",

pages = "3362--3374",

journal = "Separation Science and Technology",

issn = "0149-6395",

publisher = "Taylor and Francis Ltd.",

number = "18",

}

TY - JOUR

T1 - Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution

AU - Elaiwi, Fadhil Abid

AU - Sirkecioglu, Ahmet

PY - 2020/12/11

Y1 - 2020/12/11

N2 - In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for single ion and binary ion solutions, respectively. Data revealed that ED-MIL-101(Cr) possess maximum adsorption capacities (mg/g) of 69.9 and 63.15 for Cu(II) and Cd(II), respectively,with affinity order Cu(II) ˃ Cd(II) in binary ion solution. The kinetic data was well described by the pseudo-second-order model. The amino-functionalized MIL-101(Cr) can be a promising candidate for metal ion removal from the aqueous environment.

AB - In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for single ion and binary ion solutions, respectively. Data revealed that ED-MIL-101(Cr) possess maximum adsorption capacities (mg/g) of 69.9 and 63.15 for Cu(II) and Cd(II), respectively,with affinity order Cu(II) ˃ Cd(II) in binary ion solution. The kinetic data was well described by the pseudo-second-order model. The amino-functionalized MIL-101(Cr) can be a promising candidate for metal ion removal from the aqueous environment.

KW - Adsorption

KW - Amine functionalized MIL-101(Cr)

KW - Cadmium

KW - Copper

UR - http://www.scopus.com/inward/record.url?scp=85077171047&partnerID=8YFLogxK

U2 - 10.1080/01496395.2019.1706571

DO - 10.1080/01496395.2019.1706571

M3 - Article

AN - SCOPUS:85077171047

SN - 0149-6395

VL - 55

SP - 3362

EP - 3374

JO - Separation Science and Technology

JF - Separation Science and Technology

IS - 18

ER -

Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this