Advanced oxidation of acid and reactive dyes: Effect of Fenton treatment on aerobic, anoxic and anaerobic processes

Idil Arslan-Alaton*, Betul Hande Gursoy, Jens Ejbye Schmidt

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

141 Citations (Scopus)

Abstract

The effect of untreated and Fenton-treated acid dyes (C.I. Acid Red 183 and C.I. Acid Orange 51) and a reactive dye (C.I. Reactive Blue 4) on aerobic, anoxic and anaerobic processes was investigated. The optimum Fe2+:H2O2 molar ratio was selected as 1:5 (4 mM:20 mM) for 10 min Fenton treatment at pH 3, resulting in reduced chemical oxygen demand and dissolved organic carbon removal efficiencies; only acetate was detected as a stable dye oxidation end product. During anaerobic digestion, 100, 29% and no inhibition in methane production was observed for the untreated blue, red and orange dyes, respectively. The inhibitory effect of the blue reactive dye on methane production was ∼21% after Fenton treatment. Neither untreated nor treated dyes exhibited an inhibitory effect on denitrification. Aerobic glucose degradation was inhibited by 23-29% by untreated dyes, whereas Fenton-treated dyes had no inhibitory effect on aerobic glucose degradation.

Original languageEnglish
Pages (from-to)117-130
Number of pages14
JournalDyes and Pigments
Volume78
Issue number2
DOIs
Publication statusPublished - Aug 2008

Funding

The present work was financially supported by TUBA (The Turkish Academy of Sciences) under the “Young Scientists Scholarship Program” and conducted in the laboratories of Technical University of Denmark (Fenton, anaerobic, anoxic experiments) and Istanbul Technical University (Fenton, aerobic experiments).

FundersFunder number
TUBA
Türkiye Bilimler Akademisi
Danmarks Tekniske Universitet
Istanbul Teknik Üniversitesi

    Keywords

    • Acid dyes
    • Aerobic, anoxic and aerobic treatment processes
    • Dyehouse effluent
    • Fenton treatment
    • Reactive dyes

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