ABA-type block copolymers containing poly(dimethylsiloxane) and ketonic resins

Nurseli Uyanik; Nilgun Kizilcan; Ahmet Akar

doi:10.1002/(SICI)1097-4628(19980124)67:4<643::AID-APP7>3.0.CO;2-E

ABA-type block copolymers containing poly(dimethylsiloxane) and ketonic resins

Nurseli Uyanik^*, Nilgun Kizilcan, Ahmet Akar

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Block copolymer containing segments of poly(dimethylsiloxane) (PDMS) and ketonic resins were synthesized. Dihydroxy-terminated PDMS were reacted with the isophorone diisocyanate (IPDI) to obtain the diisocyanate-terminated PDMSs (urethane). These urethanes were reacted with reactive hydroxyl groups in the cyclohexanone-formaldehyde, acetophenone-formaldehyde, and in situ melamine-modified cyclohexanone-formaldehyde resins. Formation of block copolymers was illustrated by several characterization methods, such as chemical and spectroscopic analysis and gel permeation Chromatography. The solubilities of the block copolymers were determined, and their surface properties were investigated by contact angle measurement.

Original language	English
Pages (from-to)	643-648
Number of pages	6
Journal	Journal of Applied Polymer Science
Volume	67
Issue number	4
DOIs	https://doi.org/10.1002/(SICI)1097-4628(19980124)67:4<643::AID-APP7>3.0.CO;2-E
Publication status	Published - 24 Jan 1998

Keywords

Copolymers
Ketonic resins
Poly(dimethylsiloxane)

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10.1002/(SICI)1097-4628(19980124)67:4<643::AID-APP7>3.0.CO;2-E

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abstract = "Block copolymer containing segments of poly(dimethylsiloxane) (PDMS) and ketonic resins were synthesized. Dihydroxy-terminated PDMS were reacted with the isophorone diisocyanate (IPDI) to obtain the diisocyanate-terminated PDMSs (urethane). These urethanes were reacted with reactive hydroxyl groups in the cyclohexanone-formaldehyde, acetophenone-formaldehyde, and in situ melamine-modified cyclohexanone-formaldehyde resins. Formation of block copolymers was illustrated by several characterization methods, such as chemical and spectroscopic analysis and gel permeation Chromatography. The solubilities of the block copolymers were determined, and their surface properties were investigated by contact angle measurement.",

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AU - Uyanik, Nurseli

AU - Kizilcan, Nilgun

AU - Akar, Ahmet

PY - 1998/1/24

Y1 - 1998/1/24

N2 - Block copolymer containing segments of poly(dimethylsiloxane) (PDMS) and ketonic resins were synthesized. Dihydroxy-terminated PDMS were reacted with the isophorone diisocyanate (IPDI) to obtain the diisocyanate-terminated PDMSs (urethane). These urethanes were reacted with reactive hydroxyl groups in the cyclohexanone-formaldehyde, acetophenone-formaldehyde, and in situ melamine-modified cyclohexanone-formaldehyde resins. Formation of block copolymers was illustrated by several characterization methods, such as chemical and spectroscopic analysis and gel permeation Chromatography. The solubilities of the block copolymers were determined, and their surface properties were investigated by contact angle measurement.

AB - Block copolymer containing segments of poly(dimethylsiloxane) (PDMS) and ketonic resins were synthesized. Dihydroxy-terminated PDMS were reacted with the isophorone diisocyanate (IPDI) to obtain the diisocyanate-terminated PDMSs (urethane). These urethanes were reacted with reactive hydroxyl groups in the cyclohexanone-formaldehyde, acetophenone-formaldehyde, and in situ melamine-modified cyclohexanone-formaldehyde resins. Formation of block copolymers was illustrated by several characterization methods, such as chemical and spectroscopic analysis and gel permeation Chromatography. The solubilities of the block copolymers were determined, and their surface properties were investigated by contact angle measurement.

KW - Copolymers

KW - Ketonic resins

KW - Poly(dimethylsiloxane)

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DO - 10.1002/(SICI)1097-4628(19980124)67:4<643::AID-APP7>3.0.CO;2-E

M3 - Article

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SN - 0021-8995

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JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

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ER -

ABA-type block copolymers containing poly(dimethylsiloxane) and ketonic resins

Abstract

Keywords

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