A study of the metal complexing of naphtalene-2,3-crown ethers using flourescense spectroscopy: Part III

Gönül Yapar; Çakil Erk

doi:10.1016/S0143-7208(00)00101-7

A study of the metal complexing of naphtalene-2,3-crown ethers using flourescense spectroscopy: Part III

Gönül Yapar, Çakil Erk^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

2,3-Dioxanaphthalene derivatives of [3_n]crown-n macrocycles were synthesised from 2,3-dihydroxynaphthalene and polyglycoldihalides and studied for their cationic recognition properties using steady state fluorescence spectroscopy. The association constants for the interaction of 2,3-naphtho[12]crown-4, 2,3-naphtho[15]crown-5 and 2,3-naphto[18]crown-6 tho[18]crown-6 with LiCIO₄, NaCIO₄, NaSCN, and KSCN were measured in acetonitrile. Excellent correlation of spectroscopic, cationic charge-radii and macrocycle backbone size data was found.

Original language	English
Pages (from-to)	173-177
Number of pages	5
Journal	Dyes and Pigments
Volume	48
Issue number	3
DOIs	https://doi.org/10.1016/S0143-7208(00)00101-7
Publication status	Published - Mar 2001

Funding

The Turkish National Planning Organization, DPT is gratefully acknowledged by the authors for its support of Istanbul Technical University project P-126.

Funders	Funder number
Turkish National Planning Organization
Istanbul Teknik Üniversitesi	P-126

Keywords

Cationic recognition
Flourescense spectroscopy
Macrocycle
Naphthalene crown ethers

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10.1016/S0143-7208(00)00101-7

Cite this

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title = "A study of the metal complexing of naphtalene-2,3-crown ethers using flourescense spectroscopy: Part III",

abstract = "2,3-Dioxanaphthalene derivatives of [3n]crown-n macrocycles were synthesised from 2,3-dihydroxynaphthalene and polyglycoldihalides and studied for their cationic recognition properties using steady state fluorescence spectroscopy. The association constants for the interaction of 2,3-naphtho[12]crown-4, 2,3-naphtho[15]crown-5 and 2,3-naphto[18]crown-6 tho[18]crown-6 with LiCIO4, NaCIO4, NaSCN, and KSCN were measured in acetonitrile. Excellent correlation of spectroscopic, cationic charge-radii and macrocycle backbone size data was found.",

keywords = "Cationic recognition, Flourescense spectroscopy, Macrocycle, Naphthalene crown ethers",

author = "G{\"o}n{\"u}l Yapar and {\c C}akil Erk",

year = "2001",

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doi = "10.1016/S0143-7208(00)00101-7",

language = "English",

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T1 - A study of the metal complexing of naphtalene-2,3-crown ethers using flourescense spectroscopy

T2 - Part III

AU - Yapar, Gönül

AU - Erk, Çakil

PY - 2001/3

Y1 - 2001/3

N2 - 2,3-Dioxanaphthalene derivatives of [3n]crown-n macrocycles were synthesised from 2,3-dihydroxynaphthalene and polyglycoldihalides and studied for their cationic recognition properties using steady state fluorescence spectroscopy. The association constants for the interaction of 2,3-naphtho[12]crown-4, 2,3-naphtho[15]crown-5 and 2,3-naphto[18]crown-6 tho[18]crown-6 with LiCIO4, NaCIO4, NaSCN, and KSCN were measured in acetonitrile. Excellent correlation of spectroscopic, cationic charge-radii and macrocycle backbone size data was found.

AB - 2,3-Dioxanaphthalene derivatives of [3n]crown-n macrocycles were synthesised from 2,3-dihydroxynaphthalene and polyglycoldihalides and studied for their cationic recognition properties using steady state fluorescence spectroscopy. The association constants for the interaction of 2,3-naphtho[12]crown-4, 2,3-naphtho[15]crown-5 and 2,3-naphto[18]crown-6 tho[18]crown-6 with LiCIO4, NaCIO4, NaSCN, and KSCN were measured in acetonitrile. Excellent correlation of spectroscopic, cationic charge-radii and macrocycle backbone size data was found.

KW - Cationic recognition

KW - Flourescense spectroscopy

KW - Macrocycle

KW - Naphthalene crown ethers

UR - https://www.scopus.com/pages/publications/0035272242

U2 - 10.1016/S0143-7208(00)00101-7

DO - 10.1016/S0143-7208(00)00101-7

M3 - Article

AN - SCOPUS:0035272242

SN - 0143-7208

VL - 48

SP - 173

EP - 177

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 3

ER -

A study of the metal complexing of naphtalene-2,3-crown ethers using flourescense spectroscopy: Part III

Abstract

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Keywords

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