A simple route to synthesis of branched and cross-linked polymers with clickable moieties by photopolymerization

Mustafa Ciftci; Muhammet U. Kahveci; Yusuf Yagci; Xavier Allonas; Christian Ley; Haja Tar

doi:10.1039/c2cc35607d

A simple route to synthesis of branched and cross-linked polymers with clickable moieties by photopolymerization

Mustafa Ciftci, Muhammet U. Kahveci, Yusuf Yagci^*, Xavier Allonas, Christian Ley, Haja Tar

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Lightly branched, hyperbranched and cross-linked polymers with clickable sites were synthesized via a modified version of self-condensing photoinitiated copolymerization of methyl acrylate (MA) with propargyl acrylate (PA). The method is based on the use of a PA monomer containing two polymerizable groups, namely acrylate and propargyl groups with different reactivities in photoinitiated free radical copolymerization with MA.

Original language	English
Pages (from-to)	10252-10254
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	82
DOIs	https://doi.org/10.1039/c2cc35607d
Publication status	Published - 19 Sept 2012

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abstract = "Lightly branched, hyperbranched and cross-linked polymers with clickable sites were synthesized via a modified version of self-condensing photoinitiated copolymerization of methyl acrylate (MA) with propargyl acrylate (PA). The method is based on the use of a PA monomer containing two polymerizable groups, namely acrylate and propargyl groups with different reactivities in photoinitiated free radical copolymerization with MA.",

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AU - Ciftci, Mustafa

AU - Kahveci, Muhammet U.

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AU - Allonas, Xavier

AU - Ley, Christian

AU - Tar, Haja

PY - 2012/9/19

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AB - Lightly branched, hyperbranched and cross-linked polymers with clickable sites were synthesized via a modified version of self-condensing photoinitiated copolymerization of methyl acrylate (MA) with propargyl acrylate (PA). The method is based on the use of a PA monomer containing two polymerizable groups, namely acrylate and propargyl groups with different reactivities in photoinitiated free radical copolymerization with MA.

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A simple route to synthesis of branched and cross-linked polymers with clickable moieties by photopolymerization

Abstract

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