A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Mehmet Kandaz; Seher Zerrin Çoruhlu; Ismail Yilmaz; Ali Riza Özkaya

doi:10.1023/A:1021359012365

A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Mehmet Kandaz^*, Seher Zerrin Çoruhlu, Ismail Yilmaz, Ali Riza Özkaya

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of Ni^II, Cu^II, Co^II and Fe^II have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with U^IVO₂ and Cu^II depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, ¹H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.

Original language	English
Pages (from-to)	877-883
Number of pages	7
Journal	Transition Metal Chemistry
Volume	27
Issue number	8
DOIs	https://doi.org/10.1023/A:1021359012365
Publication status	Published - Nov 2002

Funding

We thank the Research Fund of Sakarya University (Project no: 2000-013) and the Technical University of Istanbul for financial Support (project no: 1404).

Funders	Funder number
Istanbul Teknik Üniversitesi	1404

Access to Document

10.1023/A:1021359012365

Fingerprint

Dive into the research topics of 'A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes'. Together they form a unique fingerprint.

Cite this

Kandaz, M., Çoruhlu, S. Z., Yilmaz, I., & Özkaya, A. R. (2002). A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes. Transition Metal Chemistry, 27(8), 877-883. https://doi.org/10.1023/A:1021359012365

@article{3c15699a01a24ff1801da934b6f24c23,

title = "A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes",

abstract = "A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.",

author = "Mehmet Kandaz and {\c C}oruhlu, {Seher Zerrin} and Ismail Yilmaz and {\"O}zkaya, {Ali Riza}",

year = "2002",

month = nov,

doi = "10.1023/A:1021359012365",

language = "English",

volume = "27",

pages = "877--883",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "8",

}

Kandaz, M, Çoruhlu, SZ, Yilmaz, I & Özkaya, AR 2002, 'A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes', Transition Metal Chemistry, vol. 27, no. 8, pp. 877-883. https://doi.org/10.1023/A:1021359012365

A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes. / Kandaz, Mehmet; Çoruhlu, Seher Zerrin; Yilmaz, Ismail et al.
In: Transition Metal Chemistry, Vol. 27, No. 8, 11.2002, p. 877-883.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

AU - Kandaz, Mehmet

AU - Çoruhlu, Seher Zerrin

AU - Yilmaz, Ismail

AU - Özkaya, Ali Riza

PY - 2002/11

Y1 - 2002/11

N2 - A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.

AB - A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.

UR - http://www.scopus.com/inward/record.url?scp=0036874733&partnerID=8YFLogxK

U2 - 10.1023/A:1021359012365

DO - 10.1023/A:1021359012365

M3 - Article

AN - SCOPUS:0036874733

SN - 0340-4285

VL - 27

SP - 877

EP - 883

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 8

ER -

A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this