A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

Yusuf Yagci; Suat Yildirim; Aysen Onen

doi:10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

Yusuf Yagci^*
, Suat Yildirim
, Aysen Onen

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.

Original language	English
Pages (from-to)	527-531
Number of pages	5
Journal	Macromolecular Chemistry and Physics
Volume	202
Issue number	4
DOIs	https://doi.org/10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2
Publication status	Published - 28 Feb 2001

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title = "A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization",

abstract = "A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.",

author = "Yusuf Yagci and Suat Yildirim and Aysen Onen",

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doi = "10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2",

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T1 - A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

AU - Yagci, Yusuf

AU - Yildirim, Suat

AU - Onen, Aysen

PY - 2001/2/28

Y1 - 2001/2/28

N2 - A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.

AB - A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.

UR - https://www.scopus.com/pages/publications/0035961826

U2 - 10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

DO - 10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

M3 - Article

AN - SCOPUS:0035961826

SN - 1022-1352

VL - 202

SP - 527

EP - 531

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 4

ER -

A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

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