Abstract
Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.
| Original language | English |
|---|---|
| Pages (from-to) | 9233-9235 |
| Number of pages | 3 |
| Journal | ChemistrySelect |
| Volume | 2 |
| Issue number | 28 |
| DOIs | |
| Publication status | Published - 29 Sept 2017 |
Bibliographical note
Publisher Copyright:© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Funding
This study was supported by the Research Fund of Istanbul Technical University. AG thanks Turkish Academy of Sciences (TUBA) for partial support.
| Funders |
|---|
| Istanbul Teknik Üniversitesi |
Keywords
- hexadeca substitution
- near-IR
- phthalocyanine
- self-assembly
- supramolecular interactions
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