A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Armağan Atsay; Ilgın Nar; Esin Hamuryudan; Makbule Burkut Koçak; Ahmet Gül

doi:10.1002/slct.201702078

A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Armağan Atsay^*, Ilgın Nar, Esin Hamuryudan, Makbule Burkut Koçak, Ahmet Gül

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.

Original language	English
Pages (from-to)	9233-9235
Number of pages	3
Journal	ChemistrySelect
Volume	2
Issue number	28
DOIs	https://doi.org/10.1002/slct.201702078
Publication status	Published - 29 Sept 2017

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

This study was supported by the Research Fund of Istanbul Technical University. AG thanks Turkish Academy of Sciences (TUBA) for partial support.

Funders	Funder number
Istanbul Teknik Üniversitesi

Keywords

hexadeca substitution
near-IR
phthalocyanine
self-assembly
supramolecular interactions

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abstract = "Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.",

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AU - Nar, Ilgın

AU - Hamuryudan, Esin

AU - Koçak, Makbule Burkut

AU - Gül, Ahmet

PY - 2017/9/29

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AB - Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.

KW - hexadeca substitution

KW - near-IR

KW - phthalocyanine

KW - self-assembly

KW - supramolecular interactions

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A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Abstract

Bibliographical note

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Keywords

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