6.13 - Well-Defined Block Copolymers

M. U. Kahveci; Y. Yagci; A. Avgeropoulos; C. Tsitsilianis

doi:10.1016/B978-0-444-53349-4.00171-0

6.13 - Well-Defined Block Copolymers

M. U. Kahveci, Y. Yagci, A. Avgeropoulos, C. Tsitsilianis

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

11 Citations (Scopus)

Abstract

The current study summarizes the recent advances in the design and synthesis of well-defined block polymers of various topologies prepared by different synthetic routes involving either only one polymerization mechanism or a combination of different polymerization techniques, namely, mechanistic transformations. A remarkable achievement in living/controlled polymerization methods has encouraged the synthesis of tailor-made block copolymers with specific macromolecular architecture, chemical composition/functionality, controlled molecular weight, low molecular polydispersity, and corresponding minimized heterogeneity. Thus, this chapter focuses on the methodologies involving living/controlled polymerization techniques for preparation of polymeric materials with desired fine properties.

Original language	English
Title of host publication	Polymer Science
Subtitle of host publication	a Comprehensive Reference: Volume 1-10
Publisher	Elsevier
Pages	455-509
Number of pages	55
Volume	1-10
ISBN (Electronic)	9780080878621
DOIs	https://doi.org/10.1016/B978-0-444-53349-4.00171-0
Publication status	Published - 1 Jan 2012

Bibliographical note

Publisher Copyright:
© 2012 Elsevier B.V. All rights reserved.

Keywords

Anionic polymerization
AROP
ATRP
Block copolymers
Cationic polymerization
Coupling
CROP
Free radical polymerization
Living/controlled polymerization
Metathesis polymerization
RAFT
Transformation reaction

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abstract = "The current study summarizes the recent advances in the design and synthesis of well-defined block polymers of various topologies prepared by different synthetic routes involving either only one polymerization mechanism or a combination of different polymerization techniques, namely, mechanistic transformations. A remarkable achievement in living/controlled polymerization methods has encouraged the synthesis of tailor-made block copolymers with specific macromolecular architecture, chemical composition/functionality, controlled molecular weight, low molecular polydispersity, and corresponding minimized heterogeneity. Thus, this chapter focuses on the methodologies involving living/controlled polymerization techniques for preparation of polymeric materials with desired fine properties.",

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AU - Yagci, Y.

AU - Avgeropoulos, A.

AU - Tsitsilianis, C.

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AB - The current study summarizes the recent advances in the design and synthesis of well-defined block polymers of various topologies prepared by different synthetic routes involving either only one polymerization mechanism or a combination of different polymerization techniques, namely, mechanistic transformations. A remarkable achievement in living/controlled polymerization methods has encouraged the synthesis of tailor-made block copolymers with specific macromolecular architecture, chemical composition/functionality, controlled molecular weight, low molecular polydispersity, and corresponding minimized heterogeneity. Thus, this chapter focuses on the methodologies involving living/controlled polymerization techniques for preparation of polymeric materials with desired fine properties.

KW - Anionic polymerization

KW - AROP

KW - ATRP

KW - Block copolymers

KW - Cationic polymerization

KW - Coupling

KW - CROP

KW - Free radical polymerization

KW - Living/controlled polymerization

KW - Metathesis polymerization

KW - RAFT

KW - Transformation reaction

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VL - 1-10

SP - 455

EP - 509

BT - Polymer Science

PB - Elsevier

ER -

6.13 - Well-Defined Block Copolymers

Abstract

Bibliographical note

Keywords

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