γ-Al2O3 supported/Co-Cr-B catalyst for hydrogen evolution via NH3BH3 hydrolysis

Mehmet Sait Izgi; Ömer Şahin; Cafer Saka

doi:10.1080/10426914.2019.1594280

γ-Al₂O₃ supported/Co-Cr-B catalyst for hydrogen evolution via NH₃BH₃ hydrolysis

Mehmet Sait Izgi, Ömer Şahin, Cafer Saka^*

^*Corresponding author for this work

Siirt University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

This assay investigates the Co-Cr-B catalyst effect supported on γ-Al₂O₃ to produce hydrogen (HG) from ammonia-borane hydrolysis (ABH). For characterization of this catalyst, SEM-EDX, XRD, FTIR and BET surface area analysis were performed. The maximum hydrogen generation rate (HGR) with this catalyst used for the ABH was 3260 ml min⁻¹ g⁻¹ _catalyst. The recyclability tests for the Co-Cr-B/γ-AlO₃ catalyst on the ABH have maintained an activity of 68% even after four hydrolysis treatments. Also, the activation energy (Ea) obtained using the Co-Cr-B catalyst supported on γ-AlO₃ for the ABH was 56.06 kJ/mol.

Original language	English
Pages (from-to)	1620-1626
Number of pages	7
Journal	Materials and Manufacturing Processes
Volume	34
Issue number	14
DOIs	https://doi.org/10.1080/10426914.2019.1594280
Publication status	Published - 26 Oct 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019, © 2019 Taylor & Francis.

Keywords

BET surface area
Co-Cr-B
FTIR
NHBH
SEM-EDX
XRD
characterization
hydrogen
hydrolysis
γ-AlO

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Access to Document

10.1080/10426914.2019.1594280

Cite this

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title = "γ-Al2O3 supported/Co-Cr-B catalyst for hydrogen evolution via NH3BH3 hydrolysis",

abstract = "This assay investigates the Co-Cr-B catalyst effect supported on γ-Al2O3 to produce hydrogen (HG) from ammonia-borane hydrolysis (ABH). For characterization of this catalyst, SEM-EDX, XRD, FTIR and BET surface area analysis were performed. The maximum hydrogen generation rate (HGR) with this catalyst used for the ABH was 3260 ml min−1 g−1 catalyst. The recyclability tests for the Co-Cr-B/γ-AlO3 catalyst on the ABH have maintained an activity of 68\% even after four hydrolysis treatments. Also, the activation energy (Ea) obtained using the Co-Cr-B catalyst supported on γ-AlO3 for the ABH was 56.06 kJ/mol.",

keywords = "BET surface area, Co-Cr-B, FTIR, NHBH, SEM-EDX, XRD, characterization, hydrogen, hydrolysis, γ-AlO",

author = "\{Sait Izgi\}, Mehmet and {\"O}mer {\c S}ahin and Cafer Saka",

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T1 - γ-Al2O3 supported/Co-Cr-B catalyst for hydrogen evolution via NH3BH3 hydrolysis

AU - Sait Izgi, Mehmet

AU - Şahin, Ömer

AU - Saka, Cafer

PY - 2019/10/26

Y1 - 2019/10/26

N2 - This assay investigates the Co-Cr-B catalyst effect supported on γ-Al2O3 to produce hydrogen (HG) from ammonia-borane hydrolysis (ABH). For characterization of this catalyst, SEM-EDX, XRD, FTIR and BET surface area analysis were performed. The maximum hydrogen generation rate (HGR) with this catalyst used for the ABH was 3260 ml min−1 g−1 catalyst. The recyclability tests for the Co-Cr-B/γ-AlO3 catalyst on the ABH have maintained an activity of 68% even after four hydrolysis treatments. Also, the activation energy (Ea) obtained using the Co-Cr-B catalyst supported on γ-AlO3 for the ABH was 56.06 kJ/mol.

AB - This assay investigates the Co-Cr-B catalyst effect supported on γ-Al2O3 to produce hydrogen (HG) from ammonia-borane hydrolysis (ABH). For characterization of this catalyst, SEM-EDX, XRD, FTIR and BET surface area analysis were performed. The maximum hydrogen generation rate (HGR) with this catalyst used for the ABH was 3260 ml min−1 g−1 catalyst. The recyclability tests for the Co-Cr-B/γ-AlO3 catalyst on the ABH have maintained an activity of 68% even after four hydrolysis treatments. Also, the activation energy (Ea) obtained using the Co-Cr-B catalyst supported on γ-AlO3 for the ABH was 56.06 kJ/mol.

KW - BET surface area

KW - Co-Cr-B

KW - FTIR

KW - NHBH

KW - SEM-EDX

KW - XRD

KW - characterization

KW - hydrogen

KW - hydrolysis

KW - γ-AlO

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DO - 10.1080/10426914.2019.1594280

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